Summary of Classification and Labelling
Harmonised classification - Annex VI of Regulation (EC) No 1272/2008 (CLP Regulation)
General Information
Index Number EC / List no. CAS Number International Chemical Identification
607-034-00-0 202-500-6 96-33-3 methyl acrylate
methyl propenoate

ATP Inserted / Updated: CLP00
CLP Classification (Table 3)
Classification Labelling Specific Concentration limits, M-Factors, Acute Toxicity Estimates (ATE) Notes
Hazard Class and Category Code(s) Hazard Statement Code(s) Hazard Statement Code(s) Supplementary Hazard Statement Code(s) Pictograms, Signal Word Code(s)
Flam. Liq. 2 H225 H225 GHS02
GHS07
Dgr
Note D
Acute Tox. 4 * H302 H302
Acute Tox. 4 * H312 H312
Skin Irrit. 2 H315 H315
Eye Irrit. 2 H319 H319
Skin Sens. 1 H317 H317
Acute Tox. 4 * H332 H332
STOT SE 3 H335 H335

Signal Words Pictograms
Danger
GHS02
Flame
GHS07
Exclamation mark
Seveso III Data
Disclaimer: Please note that some of the substances covered by the Seveso Directive can belong to more than one Seveso categories. It will be up to the users to decide whether their substance or mixture fall in one or in more of these classification categories depending on the tonnage bands and the concentrations.
Please also note that ECHA is not an authority for the Seveso Directive and that the Seveso categorisation below is provided for information only. The Seveso III Directive (Directive 2012/18/EU repealing Directive 96/82/EC (Seveso II) from 1 June 2015) is the only authentic legal reference and that the information in this inventory does not constitute legal advice. For further information on Seveso, please ask your national authority.

Seveso Data
Seveso Substance Seveso Categories
Da Named
P5a
P5b
P5c
Notified classification and labelling
General Information
EC / List no.
Name CAS Number
202-500-6 methyl acrylate; methyl propenoate 96-33-3

Notified classification and labelling according to CLP criteria
Classification Labelling Specific Concentration limits, M-Factors Notes Classification affected by Impurities / Additives

Additional Notified Information

Number of Notifiers

Joint Entries

Hazard Class and Category Code(s) Hazard Statement Code(s) Hazard Statement Code(s) Supplementary Hazard Statement Code(s) Pictograms, Signal Word Code(s)
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
State/Form
59 yes View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1B H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:Respirato...) (inhalation) H335
Aquatic Chronic 3 H412 H412
Flam. Liq. 2 H225 H225 GHS02
GHS07
Dgr
Note D
State/Form
362 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 H335
Flam. Liq. 2 H225 H225 GHS02
GHS07
Dgr
Note D
State/Form
103 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 H335
STOT SE 3 H335 (other:-) H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
STOT SE 3; : C ≥ 10 %
State/Form
87 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:not avail...) H335
STOT SE 3 H335 (not available) H335
Aquatic Chronic 3 H412 H412
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
State/Form
82 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1B H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 H335
Aquatic Chronic 3 H412 H412
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
68 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (Respiratory tra...) (inhalation) H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
State/Form
63 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:respirato...) H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
State/Form
60 View details
Acute Tox. 4 H302  
  H302+H312
Acute Tox. 4 H312  
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (Respiratory Sys...) H335
Aquatic Chronic 3 H412 H412
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
38 View details
Acute Tox. 4 H302  
  H302+H312
Acute Tox. 4 H312  
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (Lungs) H335
STOT SE 3 H335 (lungs) H335
Aquatic Chronic 3 H412 H412
Flam. Liq. 2 H225 H225 GHS07
GHS02
Dgr
Note D
36 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (Not applicable) H335
STOT SE 3 H335 (other:Not appli...) H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
28 View details
Acute Tox. 4 H302  
  H302+H312
Acute Tox. 4 H312  
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:Respirato...) H335
Aquatic Chronic 3 H412 H412
  H225 GHS02
GHS07
Dgr
State/Form
25 View details
  H302
  H312
  H315
  H317
  H319
  H332
  H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
State/Form
25 View details
Acute Tox. 4 H302  
  H302+H312
Acute Tox. 4 H312  
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (Respiratory sys...) H335
  H412
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
STOT SE 3; : C ≥ 10 %
State/Form
22 View details
Acute Tox. 3 H301 H301
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (lungs) H335
Flam. Liq. 2 H225 H225 GHS07
GHS02
Dgr
State/Form
16 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (Respiratory sys...) H335
STOT SE 3 H335 (other:Respirato...) H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
State/Form
14 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (Unknown) H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
13 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:respirato...) (inhalation) H335
Flam. Liq. 2 H225 H225 GHS07
GHS02
Dgr
State/Form
12 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
State/Form
11 View details
Acute Tox. 3 H301 H301
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 H335
Flam. Liq. 2 H225 H225 GHS07
GHS02
GHS06
Dgr
Note D
State/Form
11 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:-) H335
Aquatic Chronic 3 H412 H412
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
State/Form
8 View details
Acute Tox. 4 H302  
  H302+H312
Acute Tox. 4 H312  
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:Respirato...) H335
Aquatic Chronic 3 H412 H412
Flam. Liq. 2 H225 H225 GHS07
GHS02
GHS09
GHS06
Dgr
State/Form
7 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (Respiratory sys...) H335
STOT SE 3 H335 (other:Respirato...) H335
Aquatic Chronic 2 H411 H411
Flam. Liq. 2 H225 H225 (H225) GHS02
GHS07
Dgr
Note D
5 View details
Acute Tox. 4 H302 H302 (H302)
Acute Tox. 4 H312 H312 (H312)
Skin Irrit. 2 H315 H315 (H315)
Skin Sens. 1 H317 H317 (H317)
Eye Irrit. 2 H319 H319 (H319)
Acute Tox. 4 H332 H332 (H332)
STOT SE 3 H335 (other:eyes, res...) H335 (H335)
STOT SE 3 H335 (eyes, respirato...) H335 (H335)
Flam. Liq. 2 H225 H225 GHS07
GHS02
Dgr
Note D
State/Form
3 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
  H335
Flam. Liq. 2 H225 H225 GHS07
GHS02
Dgr
2 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (Respiratory Sys...) H335
Flam. Liq. 2 H225 H225 GHS02
GHS07
Dgr
Note D
State/Form
2 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:-) H335
Flam. Liq. 2 H225 H225 GHS02
GHS07
Dgr
State/Form
1 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:respirato...) H335
Flam. Liq. 2 H225 H225 GHS07
GHS02
Dgr
Note D
State/Form
1 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:respirato...) H335
Flam. Liq. 2 H225 H225 GHS02
GHS07
Dgr
State/Form
1 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:not ident...) H335
STOT SE 3 H335 (not identified) H335
Flam. Liq. 2 H225   Dgr
1 View details
Acute Tox. 4 H302  
Acute Tox. 4 H312  
Skin Irrit. 2 H315  
Skin Sens. 1 H317  
Eye Irrit. 2 H319  
Acute Tox. 4 H332  
STOT SE 3 H335 (other:not known)  
STOT SE 3 H335 (not known)  
  NA
Not Classified               1  
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
1 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
State/Form
1 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
  H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
1 View details
Acute Tox. 3 H301 H301
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (Not applicable) H335
STOT SE 3 H335 (other:Not appli...) H335
Aquatic Chronic 3 H412 H412
Flam. Liq. 2 H225 H225 GHS07
GHS02
Dgr
State/Form
1 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:respirato...) (inhalation) H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
Note D
1 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:-) H335
STOT SE 3 H335 H335
Flam. Liq. 2 H225 H225 GHS07
GHS02
Dgr
State/Form
1 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:organs) H335
STOT SE 3 H335 (organs) H335
Flam. Liq. 2 H225 H225 GHS07
GHS02
GHS06
Dgr
Note D
1 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 H335
Aquatic Chronic 3 H412 H412
Flam. Liq. 2 H225 H225 GHS07
GHS02
GHS06
Dgr
State/Form
1 View details
Acute Tox. 3 H301 H301
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2A H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (Respiratory tra...) (inhalation) H335
Flam. Liq. 2 H225 H225 GHS02
GHS06
Dgr
7546; : 0 % ≤ C < 100 %
Note D
1 View details
Acute Tox. 4 H302 H302
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 H335
Aquatic Chronic 3 H412 H412
Flam. Liq. 2 H225 H225 GHS02
GHS07
GHS06
Dgr
State/Form
1 View details
Acute Tox. 3 H301 H301
Acute Tox. 4 H312 H312
Skin Irrit. 2 H315 H315
Skin Sens. 1 H317 H317
Eye Irrit. 2A H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:Respirato...) (inhalation) H335

Number of Aggregated Notifications: 41