Summary of Classification and Labelling
Notified classification and labelling
General Information
EC / List no.
Name CAS Number
500-040-3 4,4'-Methylenediphenyl diisocyanate, oligomers 25686-28-6

Notified classification and labelling according to CLP criteria
Classification Labelling Specific Concentration limits, M-Factors Notes Classification affected by Impurities / Additives

Additional Notified Information

Number of Notifiers

Joint Entries

Hazard Class and Category Code(s) Hazard Statement Code(s) Hazard Statement Code(s) Supplementary Hazard Statement Code(s) Pictograms, Signal Word Code(s)
Skin Irrit. 2 H315 H315 EUH204
GHS08
GHS07
Dgr
Resp. Sens. 1; : C ≥ .1 %
STOT SE 3; : C ≥ 5 %
Eye Irrit. 2; : C ≥ 5 %
Skin Irrit. 2; : C ≥ 5 %
Note 2
Note C
State/Form
90 yes View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:other: re...) (inhalation) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:other: re...) (inhalation) H373 (respiratory sys...)
Skin Irrit. 2 H315 H315 GHS08
GHS07
Dgr
441 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:unknown) H335
Skin Irrit. 2 H315 H315 GHS07
GHS08
Dgr
184 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:respirato...) H335
Skin Irrit. 2 H315 H315 GHS08
GHS07
Dgr
State/Form
87 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (not available) H335
STOT SE 3 H335 (other:not avail...) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:not avail...) H373
STOT RE 2 H373 (not available) H373
Not Classified               72  
Skin Irrit. 2 H315 H315 EUH204
GHS08
GHS07
Dgr
Skin Irrit. 2; : C ≥ 5 %
STOT SE 3; : C ≥ 5 %
Eye Irrit. 2; : C ≥ 5 %
State/Form
58 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:...) H335
STOT SE 3 H335 (...) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) (inhalation) H373 (respiratory sys...)
Skin Irrit. 2 H315 H315 GHS08
GHS07
Dgr
37 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (Atmungssystem) H335
Carc. 2 H351 H351
STOT RE 2 H373 (Lunge) (inhalation) H373
Skin Irrit. 2 H315 H315 GHS07
GHS08
Dgr
yes 27 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (not identified) H335
Skin Irrit. 2 H315 H315 EUH204
GHS08
GHS07
Dgr
Eye Irrit. 2; : C ≥ 5 %
Resp. Sens. 1; : C ≥ .1 %
Skin Irrit. 2; : C ≥ 5 %
STOT SE 3; : C ≥ 5 %
27 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:other: re...) (inhalation) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:other: re...) (inhalation) H373
Acute Tox. 4 H302 H302 GHS08
GHS07
Dgr
22 View details
Skin Irrit. 2 H315 H315
Skin Sens. 1A H317 H317
Eye Irrit. 2 H319 H319
Resp. Sens. 1A H334 H334
STOT SE 3 H335 (other:respirato...) (inhalation) H335
STOT RE 2 H373 (other:respirato...) (inhalation) H373
Skin Irrit. 2 H315 H315 EUH204
GHS07
GHS08
Dgr
STOT SE 3; : C ≥ 5 %
Skin Irrit. 2; : C ≥ 5 %
Eye Irrit. 2; : C ≥ 5 %
State/Form
19 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (lungs) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) (inhalation) H373 (respiratory sys...)
Skin Irrit. 2 H315 H315 GHS08
GHS07
Dgr
Resp. Sens. 1; : C ≥ .1 %
Eye Irrit. 2; : C ≥ 5 %
7546; : C ≥ 1 %
Skin Irrit. 2; : C ≥ 5 %
STOT SE 3; : C ≥ 5 %
STOT RE 2; : C ≥ 10 %
State/Form
18 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (Respiratory sys...) H335
Carc. 2 H351 H351
STOT RE 2 H373 (Respiratory Tra...) (inhalation) H373
Skin Irrit. 2 H315 H315 GHS07
GHS08
Dgr
State/Form
16 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (not specified) H335
Skin Irrit. 2 H315 H315 EUH204
GHS08
GHS07
Dgr
Skin Irrit. 2; : C ≥ 5 %
STOT SE 3; : C ≥ 5 %
Eye Irrit. 2; : C ≥ 5 %
13 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (...) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) (inhalation) H373
Skin Irrit. 2 H315 H315 GHS07
GHS08
Dgr
State/Form
10 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:not ident...) H335
STOT SE 3 H335 (not identified) H335
Skin Irrit. 2 H315 H315 GHS08
GHS07
Dgr
State/Form
8 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:respirato...) (inhalation) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) (inhalation) H373
Skin Irrit. 2 H315 H315 EUH204
GHS08
GHS07
Dgr
Eye Irrit. 2; : C ≥ 5 %
Skin Irrit. 2; : C ≥ 5 %
Resp. Sens. 1; : C ≥ .1 %
STOT SE 3; : C ≥ 5 %
State/Form
6 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:respirato...) (inhalation) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) (inhalation) H373
Skin Irrit. 2 H315 H315 EUH204
GHS07
GHS08
Dgr
STOT SE 3; : C ≥ 5 %
Eye Irrit. 2; : C ≥ 5 %
Skin Irrit. 2; : C ≥ 5 %
State/Form
3 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (Not provided) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) (inhalation) H373 (respiratory sys...)
Skin Irrit. 2 H315 H315 GHS07
GHS08
Dgr
STOT SE 3; : 5 % ≤ C < 100 %
Eye Irrit. 2; : 5 % ≤ C < 100 %
Resp. Sens. 1; : .1 % ≤ C < 100 %
Skin Irrit. 2; : 5 % ≤ C < 100 %
3 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:Not appli...) H335
STOT SE 3 H335 (Not applicable) H335
Carc. 2 H351 H351 (Suspected of ca...)
STOT RE 2 H373 (other:respirato...) H373 (May cause damag...)
Skin Irrit. 2 H315 H315 EUH204
GHS07
GHS08
Dgr
Eye Irrit. 2; : C ≥ 5 %
Resp. Sens. 1; : C ≥ .1 %
Skin Irrit. 2; : C ≥ 5 %
STOT SE 3; : C ≥ 5 %
Note 2
Note C
State/Form
2 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:respirato...) (inhalation) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) (inhalation) H373 (respiratory sys...)
Skin Irrit. 2 H315 H315 GHS07
GHS08
Dgr
Eye Irrit. 2; : 5 % ≤ C < 100 %
Skin Irrit. 2; : 5 % ≤ C < 100 %
Resp. Sens. 1; : .1 % ≤ C < 100 %
2 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
Carc. 2 H351 H351 (Suspected of ca...)
STOT RE 2 H373 (other:respirato...) H373 (May cause damag...)
Skin Irrit. 2 H315 H315 EUH204
GHS08
GHS07
Dgr
State/Form
2 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:Lung) H335
STOT SE 3 H335 (Lung) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:Lung) H373
STOT RE 2 H373 (Lung) H373
Skin Irrit. 2 H315 H315 GHS07
GHS08
Dgr
Skin Irrit. 2; : 5 % ≤ C < 100 %
Eye Irrit. 2; : 5 % ≤ C < 100 %
STOT SE 3; : 5 % ≤ C < 100 %
Resp. Sens. 1; : .1 % ≤ C < 100 %
2 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (Not applicable) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) H373
Skin Irrit. 2 H315 H315 GHS07
GHS08
Dgr
Eye Irrit. 2; : 5 % ≤ C < 100 %
STOT SE 3; : 5 % ≤ C < 100 %
Skin Irrit. 2; : 5 % ≤ C < 100 %
Resp. Sens. 1; : .1 % ≤ C < 100 %
2 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 H335
Carc. 2 H351 H351
STOT RE 2 H373 H373
Skin Irrit. 2 H315 H315 EUH204
GHS07
GHS08
Dgr
1 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:respirato...) (inhalation) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) (inhalation) H373
Skin Irrit. 2 H315 H315 EUH204
GHS08
GHS07
Dgr
Eye Irrit. 2; : C ≥ 5 %
STOT SE 3; : C ≥ 5 %
Skin Irrit. 2; : C ≥ 5 %
Resp. Sens. 1; : C ≥ .1 %
yes 1 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 (other:respirato...) (inhalation) H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) (inhalation) H373
Skin Irrit. 2 H315 H315 GHS08
GHS07
Dgr
STOT SE 3; : 5 % ≤ C < 100 %
Eye Irrit. 2; : 5 % ≤ C < 100 %
STOT RE 2; : 0 % ≤ C < 100 %
7546; : 0 % ≤ C < 100 %
Skin Irrit. 2; : 5 % ≤ C < 100 %
Resp. Sens. 1; : .1 % ≤ C < 100 %
1 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 H335
Carc. 2 H351 H351
STOT RE 2 H373 H373
Skin Irrit. 2 H315 H315 GHS07
GHS08
Dgr
Eye Irrit. 2; : 5 % ≤ C < 100 %
STOT RE 2; : 0 % ≤ C < 100 %
STOT SE 3; : 5 % ≤ C < 100 %
7546; : 0 % ≤ C < 100 %
Skin Irrit. 2; : 5 % ≤ C < 100 %
Resp. Sens. 1; : .1 % ≤ C < 100 %
1 View details
Skin Sens. 1 H317 H317
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
Resp. Sens. 1 H334 H334
STOT SE 3 H335 H335
Carc. 2 H351 H351
STOT RE 2 H373 (other:respirato...) H373

Number of Aggregated Notifications: 28