Registration Dossier
Registration Dossier
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EC number: 424-620-1 | CAS number: 13909-63-2 TUPH
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
· General information:
Remove contaminated clothing.
Symptoms of poisoning may occur after several hours. Medical observation for at least 48 hours after the accident is recommended.
· After inhalation: Supply fresh air; consult doctor in case of symptoms.
· After skin contact: Wash with soap and water. If skin irritation continues, consult a doctor.
· After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor.
Remove contact lenses, if present and easy to do. Continue rinsing.
· After swallowing: Rinse out mouth and then drink plenty of water. Get medical advice/attention if you feel unwell.
Fire-fighting measures
· Suitable extinguishing agents
Carbon dioxide (CO₂), extinguishing powder or water spray/fog. Fight larger fires with water spray/fog or
alcohol-resistant foam.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
Special hazards arising from the substance or mixture
Sulphur oxides (SOx)
Nitrogen oxides (NOx)
Carbon monoxide (CO) and Carbon dioxide (CO₂)
Risk of dust explosion.
Advice for firefighters
· Protective equipment: Wear self-contained breathing apparatus.
· Additional information
Cool endangered containers with water spray jet.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
If without risk possible, move drums with material away from dangerous area.
Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation.
Avoid causing dust.
Remove all ignition sources.
Do not breathe dust.
Avoid contact with skin and eyes.
· Environmental precautions:
Do not allow product to reach sewage system or water bodies.
Inform respective authorities in case product reaches water or sewage system.
· Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Send for recovery or disposal in suitable containers.
Dispose of the material collected according to regulations.
Handling and storage
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of dust.
Any deposit of dust which cannot be avoided must be removed regularly.
Do not breathe dust.
Avoid prolonged or repeated skin contact.
Avoid contact with eyes.
· Information about protection against explosions and fires:
Dust can combine with air to form an explosive mixture.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers:
Store only in the original container.
Observe all local and national regulations for storage of water polluting products.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Store container in a well ventilated position.
Store in cool, dry conditions in well sealed containers.
Protect from heat and direct sunlight.
Protect from humidity and keep away from water.
Store in the dark.
Transport information
Land transport (UN RTDG/ADR/RID)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- no dangerous good for transport
Inland waterway transport (UN RTDG/ADN(R))
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- no dangerous good for transport
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- no dangerous good for transport
Air transport (UN RTDG/ICAO/IATA)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- no dangerous good for transport
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Do not eat, drink or smoke while working.
Instantly remove any contaminated garments.
Do not breathe dust.
Avoid close or long term contact with the skin.
Avoid contact with the eyes.
Wash hands during breaks and at the end of the work.
· Breathing equipment:
Use breathing protection in case of dust formation.
Dust proof mask - particle filter mask
· Protection of hands:
Protective gloves
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Check the permeability prior to each renewed use of the glove.
To avoid skin problems reduce the wearing of gloves to the required minimum.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
· Penetration time of glove material
Protective gloves should be replaced at first signs of wear.
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection: Safety glasses
· Body protection:
Protective work clothing
Body protection must be chosen depending on activity and possible exposure.
Stability and reactivity
Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Avoid impact, friction, heat, sparks, electrostatic charges.
· Possibility of hazardous reactions Risk of dust explosion.
· Incompatible materials: Strong oxidizing agents
· Hazardous decomposition products:
Sulphur oxides (SOx)
Nitrogen oxides (NOx)
Carbon monoxide (CO) and Carbon dioxide (CO₂)
Disposal considerations
Waste treatment methods
· Recommendation Disposal must be made according to official regulations.
· European waste catalogue:
Waste disposal key numbers from EWC have to be assigned depending on origin and processing.
Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulatio
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
