Tin(II) oxalate

Guidance on Safe Use

First-aid measures

· 4.1 Description of first aid measures

· General information Remove contaminated clothing.

· After inhalation Supply fresh air; consult doctor in case of symptoms.

· After skin contact

Immediately wash with water and soap and rinse thoroughly.

If skin irritation continues, consult a doctor.

· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.

· After swallowing Instantly call for doctor.

4.2 Most important symptoms and effects, both acute and delayed

No further relevant information available.

· 4.3 Indication of any immediate medical attention and special treatment needed

No further relevant information available.

Fire-fighting measures

· 5.1 Extinguishing media

· Suitable extinguishing agents

Contain and let it cool down with heat-resistant material (for example, dry sand).

· For safety reasons unsuitable extinguishing agents Water.

· 5.2 Special hazards arising from the substance or mixture

Formation of toxic gases is possible during heating or in case of fire.

- tin oxide

- carbon dioxide, carbon monoxide

· 5.3 Advice for firefighters

· Protective equipment: Do not inhale explosion gases or combustion gases.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Wear protective clothing.

Avoid causing dust.

· 6.2 Environmental precautions:

Do not allow product to reach sewage system or water bodies.

Do not allow to enter the ground/soil.

· 6.3 Methods and material for containment and cleaning up:

Collect mechanically.

Dispose of contaminated material as waste according to item 13.

Ensure adequate ventilation.

· 6.4 Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for information on disposal.

Handling and storage

· 7.1 Precautions for safe handling Prevent formation of dust.

· Information about protection against explosions and fires:

Protect against electrostatic charges.

· 7.2 Conditions for safe storage, including any incompatibilities

· Storage

· Requirements to be met by storerooms and containers: No special requirements.

· Information about storage in one common storage facility: Not required.

· Further information about storage conditions:

Keep container tightly sealed.

Store in a cool place.

Store under dry conditions.

· Storage class LGK 10-13

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3261

Shipping

Labels:

8

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3261

Shipping

Labels:

8

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3261

Shipping information

Proper shipping name and description:

Corrosive solid, acidic, organic, n.o.s.

Chemical name:

TIn OXALTAE

Labels:

void

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

3261

Shipping information

Proper shipping name and description:

Corrosive solid, acidic, organic, n.o.s.

Chemical name:

TIN OXALATE

Labels:

8

Remarks

SpecialProvisions

Exposure controls / personal protection

8.2 Exposure controls

· Personal protective equipment

· General protective and hygienic measures

Take off immediately all contaminated clothing

Wash hands during breaks and at the end of the work.

Avoid contact with the eyes and skin.

· Breathing equipment: Use a breathing protection if high concentrations are present.

· Recommended filter device for short term use: Filter P2

· Protection of hands:

Protective gloves.

The glove material has to be impermeable and resistant to the product/ the substance/ the

preparation.

· Material of gloves

Rubber gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks

of quality and varies from manufacturer to manufacturer.

· Penetration time of glove material

The exact break trough time has to be found out by the manufacturer of the protective gloves and

has to be observed.

· Eye protection: Tightly sealed safety glasses.

Stability and reactivity

10.1 Reactivity No dangerous reaction known under conditions of normal use.

· 10.2 Chemical stability

No hazardous reactions if the regulations / instructions for storage and handling are considered.

· Thermal decomposition / conditions to be avoided: ≈ 280°C

· 10.3 Possibility of hazardous reactions

Risk of dust explosion if enriched with fine dust in presence of air

· 10.4 Conditions to avoid No further relevant information available.

· 10.5 Incompatible materials: No further relevant information available.

· 10.6 Hazardous decomposition products:

Carbon monoxide and carbon dioxide

tin oxide (SnO / SnO2)

Disposal considerations

· 13.1 Waste treatment methods

· Recommendation Must be specially treated under adherence to official regulations.

· Uncleaned packagings:

· Recommendation: Disposal must be made according to official regulations.

· Recommended cleaning agent: Water, if necessary with cleaning agent.