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Diss Factsheets

Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2012-05-28 to 2012-03-13
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
GLP compliance:
no
Type of method:
gas saturation method
Temp.:
25 °C
Vapour pressure:
0.094 Pa
Remarks on result:
other: with confidence interval of 0.02; the temperature is quoted as ±0.5 °C
Key result
Temp.:
20 °C
Vapour pressure:
0.083 Pa
Remarks on result:
other: with confidence interval of 0.02; the temperature is quoted as ±0.5 °C

Vapour pressure data at 25 °C

Sample name

Actual ppm in solution

Sample in g

Temperature (K)

Total gas flow (mins)

Average gas flow (seconds/100 ml)

Gas flow (L)

Total Gas Flow (M³)

RT/M

Vapour pressure (Pa)

Average vapour pressure (Pa)

% difference in gas flow rate (of extremities)

% difference in vapour pressure (of extremities)

Total average vapour pressure (Pa)

VP1

14.346241687

7.17312E-03

298.15

4250

41

0.145

0.618181818

9.165535589

0.106353006

0.106384190

47.3

35.7

0.09405

14.354654871

7.17733E-03

0.106415375

VP2

16.520307519

8.26015E-03

33

0.183

0.778625954

0.097233765

0.097379891

16.569961804

8.28498E-03

0.097526016

VP3

15.733097401

7.86655E-03

28

0.214

0.910714286

0.079169871

0.078399943

15.427088438

7.71354E-03

0.077630015

 

 

Vapour pressure data at 20 °C

Sample name

Actual ppm in solution

Sample in g

Temperature (K)

Total gas flow (mins)

Average gas flow (seconds/100 ml)

Gas flow (L)

Total Gas Flow (M³)

RT/M

Vapour pressure (Pa)

Average vapour pressure (Pa)

% difference in gas flow rate (of extremities)

% difference in vapour pressure (of extremities)

Total average vapour pressure (Pa)

VP1

12.433492870

6.21675E-03

293.15

4560

41

0.145

0.663272727

9.011828804

0.084466393

0.085667022

47.3

21.8

0.08322

12.786959282

6.39348E-03

0.086867651

VP2

16.136146864

8.06807E-03

34

0.179

0.816716418

0.089024899

0.090050903

16.508082339

8.25404E-03

0.091076908

VP3

15.899978645

7.94999E-03

28

0.214

0.977142857

0.073319824

0.073930488

16.164832854

8.08242E-03

0.074541151

 

 Acceptance criteria were achieved for the 20 °C determination but not for the 25 °C determination with the difference on vapour pressure of the extreme values being approximately 36 %. However due to the relatively low vapour pressure being measured and therefore minor differences between individual values (0.078, 0.097 and 0.106 Pa), and the relative similarity in results obtained at the two temperatures as expected, this is not expected to have significantly affected the values reported and the results are deemed acceptable.

Conclusions:
Vapour pressure: 0.094 Pa at 25 °C; 0.083 Pa at 20 °C.
Executive summary:

In a guideline test, the vapour pressure of the test substance was determined to be 0.094 Pa at 25 °C and 0.083 Pa at 20 °C.

Description of key information

Vapour pressure: 0.094 Pa at 25 °C; 0.083 Pa at 20 °C.

Key value for chemical safety assessment

Vapour pressure:
0.094 Pa
at the temperature of:
25 °C

Additional information

In a guideline test, the vapour pressure of the test substance was determined to be 0.094 Pa at 25 °C and 0.083 Pa at 20 °C.