Registration Dossier
Registration Dossier
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EC number: 619-228-2 | CAS number: 96556-05-7
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
4.1 Description of first aid measures
General advice
: Remove/Take off immediately all contaminated clothing.
Ensure that the First Aid Personnel are aware of the product involved, and take precautions to protect themselves (e.g. wear personal protection equipment).
If inhaled
: If inhaled, remove to fresh air.
Get medical advice/ attention.
In case of skin contact
: In case of contact, immediately flush skin with plenty of wa-ter.
If skin irritation persists, call a physician.
In case of eye contact
: In the case of contact with eyes, rinse immediately with plen-ty of water and seek medical advice.
If swallowed
: Do not induce vomiting. Keep patient at rest and obtain im-mediate medical assistance
If swallowed, rinse mouth with water (only if the person is conscious).
Do not give anything to drink.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms :
None known.
Risks :
None known.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment
:
Treat symptomatically.
General advice
: Remove/Take off immediately all contaminated clothing.
Ensure that the First Aid Personnel are aware of the product involved, and take precautions to protect themselves (e.g. wear personal protection equipment).
If inhaled
: If inhaled, remove to fresh air.
Get medical advice/ attention.
In case of skin contact
: In case of contact, immediately flush skin with plenty of wa-ter.
If skin irritation persists, call a physician.
In case of eye contact
: In the case of contact with eyes, rinse immediately with plen-ty of water and seek medical advice.
If swallowed
: Do not induce vomiting. Keep patient at rest and obtain im-mediate medical assistance
If swallowed, rinse mouth with water (only if the person is conscious).
Do not give anything to drink.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms :
None known.
Risks :
None known.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment
:
Treat symptomatically.
Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
: Water spray jet
Alcohol-resistant foam
Dry powder
Carbon dioxide (CO2)
Unsuitable extinguishing media
: High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting
: In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Carbon dioxide (CO2)
Nitrous gases (NOx)
5.3 Advice for firefighters
Special protective equipment for firefighters
: Self-contained breathing apparatus Full protective suit
Further information
: Cool endangered containers with water spray jet.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Suitable extinguishing media
: Water spray jet
Alcohol-resistant foam
Dry powder
Carbon dioxide (CO2)
Unsuitable extinguishing media
: High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire-fighting
: In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Carbon dioxide (CO2)
Nitrous gases (NOx)
5.3 Advice for firefighters
Special protective equipment for firefighters
: Self-contained breathing apparatus Full protective suit
Further information
: Cool endangered containers with water spray jet.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions
:
Wear suitable protective equipment.
Ventilate the area.
Mark the contaminated area with signs and prevent access to unauthorized personnel.
Information regarding Safe handling, see chapter 7.
For personal protection see section 8.
Information regarding Waste Disposal, see chapter 13.
6.2 Environmental precautions
Environmental precautions
: Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
The product should not be allowed to enter drains, water courses or the soil.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Treat recovered material as described in the section "Dis-posal considerations".
6.4 Reference to other sections
For personal protection see section 8., For disposal considerations see section 13.
Personal precautions
:
Wear suitable protective equipment.
Ventilate the area.
Mark the contaminated area with signs and prevent access to unauthorized personnel.
Information regarding Safe handling, see chapter 7.
For personal protection see section 8.
Information regarding Waste Disposal, see chapter 13.
6.2 Environmental precautions
Environmental precautions
: Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
The product should not be allowed to enter drains, water courses or the soil.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up
: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Treat recovered material as described in the section "Dis-posal considerations".
6.4 Reference to other sections
For personal protection see section 8., For disposal considerations see section 13.
Handling and storage
7.1 Precautions for safe handling
Advice on safe handling
: Use only in well-ventilated areas.
Handle and open container with care.
Avoid inhalation, ingestion and contact with skin and eyes.
Keep container tightly closed.
Keep limited supplies at workplace.
Advice on protection against fire and explosion
: Observe the general rules of industrial fire protection
Hygiene measures
: Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it before reuse.
Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Keep only in the original container.
Further information on stor-age conditions
: Keep container tightly closed in a cool, well-ventilated place, open and handle carefully. Storage: cool
Advice on common storage
: Avoid storage near incompatibile agents (see section 10).
Do not store or transport together with foodstuffs
Other data
: Shelf life is limited; see product information leaflet
7.3 Specific end use(s)
Specific use(s)
: No further recommendations.
Advice on safe handling
: Use only in well-ventilated areas.
Handle and open container with care.
Avoid inhalation, ingestion and contact with skin and eyes.
Keep container tightly closed.
Keep limited supplies at workplace.
Advice on protection against fire and explosion
: Observe the general rules of industrial fire protection
Hygiene measures
: Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it before reuse.
Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
: Keep only in the original container.
Further information on stor-age conditions
: Keep container tightly closed in a cool, well-ventilated place, open and handle carefully. Storage: cool
Advice on common storage
: Avoid storage near incompatibile agents (see section 10).
Do not store or transport together with foodstuffs
Other data
: Shelf life is limited; see product information leaflet
7.3 Specific end use(s)
Specific use(s)
: No further recommendations.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3267
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3267
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3267
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
- Chemical name:
- 1,4,7-Trimethyl-1,4,7-triazacyclononane
- Labels:
- 8
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3267
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
- Chemical name:
- 1,4,7-Trimethyl-1,4,7-triazacyclononane
- Labels:
- Corrosives
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
8.1 Control parameters
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health ef-fects Value
1,4,7-Trimethyl-1,4,7-triazacyclononane
Remarks: No data available
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
1,4,7-Trimethyl-1,4,7-triazacyclononane
Remarks:
No data available
8.2 Exposure controls
Engineering measures
See section 7; no measures in addition to the ones mentioned are necessary.
Personal protective equipment
Eye protection
: Depending on the risk, wear sufficient eye protection (safety glasses with side protection or goggles, and if necessary, face shield.)
Hand protection
Remarks
: Long-term exposure
Impervious butyl rubber gloves
For short-term exposure (splash protection):
Nitrile rubber gloves.
Skin and body protection
: Protective suit
Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.
Filter A (organic gases and vapours) to standard DIN EN 141
Protective measures
: Observe the usual precautions for handling chemicals.
Ensure that eyewash stations and safety showers are close to the workstation location.
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health ef-fects Value
1,4,7-Trimethyl-1,4,7-triazacyclononane
Remarks: No data available
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
1,4,7-Trimethyl-1,4,7-triazacyclononane
Remarks:
No data available
8.2 Exposure controls
Engineering measures
See section 7; no measures in addition to the ones mentioned are necessary.
Personal protective equipment
Eye protection
: Depending on the risk, wear sufficient eye protection (safety glasses with side protection or goggles, and if necessary, face shield.)
Hand protection
Remarks
: Long-term exposure
Impervious butyl rubber gloves
For short-term exposure (splash protection):
Nitrile rubber gloves.
Skin and body protection
: Protective suit
Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.
Filter A (organic gases and vapours) to standard DIN EN 141
Protective measures
: Observe the usual precautions for handling chemicals.
Ensure that eyewash stations and safety showers are close to the workstation location.
Stability and reactivity
10.1 Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2 Chemical stability
Decomposes upon contact with air.
10.3 Possibility of hazardous reactions
Hazardous reactions
: Reactions with acids and strong oxidising agents.
10.4 Conditions to avoid
Conditions to avoid
: Air + humidity
Heat, flames and sparks.
10.5 Incompatible materials
Materials to avoid
: Humid air
Strong acids and oxidizing agents
10.6 Hazardous decomposition products
Carbon dioxide (CO2)
Carbon monoxide
See section 10.3. "Possibility of hazardous reactions"
10.2 Chemical stability
Decomposes upon contact with air.
10.3 Possibility of hazardous reactions
Hazardous reactions
: Reactions with acids and strong oxidising agents.
10.4 Conditions to avoid
Conditions to avoid
: Air + humidity
Heat, flames and sparks.
10.5 Incompatible materials
Materials to avoid
: Humid air
Strong acids and oxidizing agents
10.6 Hazardous decomposition products
Carbon dioxide (CO2)
Carbon monoxide
Disposal considerations
13.1 Waste treatment methods
Product : Product should be taken to a suitable and authorized waste disposal site in accordance with relevant regulations and if necessary after consultation with the waste disposal operator and/or the competent Authorities
Contaminated packaging : Packaging that cannot be cleaned should be disposed of as product waste
Product : Product should be taken to a suitable and authorized waste disposal site in accordance with relevant regulations and if necessary after consultation with the waste disposal operator and/or the competent Authorities
Contaminated packaging : Packaging that cannot be cleaned should be disposed of as product waste
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
