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EC number: 278-093-4 | CAS number: 75173-68-1
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Endpoint summary
Administrative data
Description of key information
Appearance:
On the basis of physical observation and using the sense of smell, [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was observed to be a blue color liquid having amine like odor.
Freezing point:
Freezing point of chemical [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was determine to be less than -3.02 Deg C.
Boiling Point:
The boiling point of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt is determine to be 102°C.
Density:
The density of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was determine to be 1.2 gm/cm3at 25 °C.
Particle size distribution:
The study does not need to be conducted because the substance is marketed or used in a non solid or granular form. On the basis of physical observation and using the sense of smell, [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was observed to be a blue color liquid having amine like odor.
Vapour pressure:
The estimated vapour pressure of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt at 25 deg C was 2400 Pa.
Partition coefficient:
Based on the available data from modeling database using the KOWWIN V1.68 program, the partition coefficient (log Pow) value of the substance [μ-[[3,3'-[azoxybis[(2-hydroxy-p-phenylene)azo]]bis[4-hydroxynaphthalene-2,7-disulphonato]](8-)]]dicopper, tetrasodium salt was estimated to be 3.6. Thus, on the basis of logPow value, chemical [μ-[[3,3'-[azoxybis[(2-hydroxy-p-phenylene)azo]]bis[4-hydroxynaphthalene-2,7-disulphonato]](8-)]]dicopper, tetrasodium salt can be considered to be hydrophobic in nature.
Water solubility:
The water solubility determination of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was done as per the shake flask method. The solubility of chemical [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was determine to be 45 mg/L at 25 Deg C. Thus chemical [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt is considered to be slightly soluble in water.
Surface tension:
The study does not need to be conducted because based on structure, surface activity is not expected or cannot be predicted.
Flash point:
The flash point of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was determine to be greater than 100°C at 979.1 hPa.
Auto flammability:
[μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt did not catch fire on being exposed to air at room temperature of 27°C pressure of 966 hPa. This indicates that [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt is not auto-flammable.
Flammability:
[μ-[[3,3'-[azoxybis[(2-hydroxy-p-phenylene)azo]]bis[4-hydroxynaphthalene-2,7-disulphonato]](8-)]]dicopper, tetrasodium salt does not indicate any ignition when the flame of bunsen burner having temperature of approximately 950°C is brought in contact with it. Thus it can be concluded that [μ-[[3,3'-[azoxybis[(2-hydroxy-p-phenylene)azo]]bis[4-hydroxynaphthalene-2,7-disulphonato]](8-)]]dicopper, tetrasodium salt is not flammable at high temperature. However since such high temperatures are not found under normal circumstances of transportation and use, thus [μ-[[3,3'-[azoxybis[(2-hydroxy-p-phenylene)azo]]bis[4-hydroxynaphthalene-2,7-disulphonato]](8-)]]dicopper, tetrasodium salt was considered non-flammable for chemical safety assessment.
Explosiveness:
The study does not need to be conducted because there are no chemical groups present in the molecule which are associated with explosive properties.
Oxidizing properties:
The study does not need to be conducted because the substance is a liquid.
Additional information
Appearance:
On the basis of physical observation and using the sense of smell, [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was observed to be a blue color liquid having amine like odor.
Melting point:
Freezing point of chemical [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was determine to be less than -3.02 Deg C.
Boiling Point:
The boiling point determination of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was done as per the test guideline OECD 103. The method followed was according to Siwoloboff. The boiling point of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt is determine to be 102°C.
Density:
The density of chemical [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was determined following OECD guideline OECD 109 according to pycnometer method. The density of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was determine to be 1.2 gm/cm3at 25 °C.
Particle size distribution:
The study does not need to be conducted because the substance is marketed or used in a non solid or granular form. On the basis of physical observation and using the sense of smell, [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was observed to be a blue color liquid having amine like odor.
Vapour pressure:
Modified Grain method was used to estimate the vapour pressure of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt using MPBPVP v1.43 of EPI SUITE.
The estimated vapour pressure of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt at 25 deg C was 2400 Pa.
Partition coefficient:
Based on the available data from modeling database using the KOWWIN V1.68 program, the partition coefficient (log Pow) value of the substance [μ-[[3,3'-[azoxybis[(2-hydroxy-p-phenylene)azo]]bis[4-hydroxynaphthalene-2,7-disulphonato]](8-)]]dicopper, tetrasodium salt was estimated to be 3.6. Thus, on the basis of logPow value, chemical [μ-[[3,3'-[azoxybis[(2-hydroxy-p-phenylene)azo]]bis[4-hydroxynaphthalene-2,7-disulphonato]](8-)]]dicopper, tetrasodium salt can be considered to be hydrophobic in nature.
Water solubility:
The water solubility determination of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was done as per the shake flask method. The solubility of chemical [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was determine to be 45 mg/L at 25 Deg C. Thus chemical [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt is considered to be slightly soluble in water.
Surface tension:
The study does not need to be conducted because based on structure, surface activity is not expected or cannot be predicted.
Flash point:
The flash point determination of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt (CAS No. 75173 -68 -1) was done as per the test guideline OECD 103. The method is closed cup method using Pensky Martin’s Flash Point Apparatus. The flash point of [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt was determine to be greater than 100°C at 979.1 hPa.
Auto flammability:
[μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt did not catch fire on being exposed to air at room temperature of 27°C pressure of 966 hPa. This indicates that [μ-[[3,3'-[azoxybis[(2 -hydroxy-p-phenylene)azo]]bis[4 -hydroxynaphthalene-2,7 -disulphonato]](8 -)]]dicopper, tetrasodium salt is not auto-flammable.
Flammability:
[μ-[[3,3'-[azoxybis[(2-hydroxy-p-phenylene)azo]]bis[4-hydroxynaphthalene-2,7-disulphonato]](8-)]]dicopper, tetrasodium salt does not indicate any ignition when the flame of bunsen burner having temperature of approximately 950°C is brought in contact with it. Thus it can be concluded that [μ-[[3,3'-[azoxybis[(2-hydroxy-p-phenylene)azo]]bis[4-hydroxynaphthalene-2,7-disulphonato]](8-)]]dicopper, tetrasodium salt is not flammable at high temperature. However since such high temperatures are not found under normal circumstances of transportation and use, thus [μ-[[3,3'-[azoxybis[(2-hydroxy-p-phenylene)azo]]bis[4-hydroxynaphthalene-2,7-disulphonato]](8-)]]dicopper, tetrasodium salt was considered non-flammable for chemical safety assessment.
Explosiveness:
The study does not need to be conducted because there are no chemical groups present in the molecule which are associated with explosive properties.
Oxidizing properties:
The study does not need to be conducted because the substance is a liquid.
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