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Diss Factsheets

Physical & Chemical properties

Melting point / freezing point

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Reference
Endpoint:
melting point/freezing point
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 102 (Melting point / Melting Range)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.7200 (Melting Point / Melting Range)
Deviations:
no
GLP compliance:
yes
Type of method:
capillary method
Key result
Melting / freezing pt.:
84.8 °C
Atm. press.:
756.9 mm Hg
Decomposition:
no
Sublimation:
no
Remarks on result:
other: Range: 84.8 ± 0.5°C (358.0K) to 90.1 ± 0.2°C (363.3K). Upon melting the test substance was clear and colorless.

Determination of Melting Point/Melting Range for the Test Substance

Instrument Gradient (°C/min)

Barometric Pressure (mm Hg)

Start of

Melting Range

°C (K)1

End of Melting Range °C (K)1

Melting Point °C (K)1

112C-312-1

1.0

756.9

84.5 (357.7)

90.2 (363.4)

 

84.5 (357.7)

112C-312-2

1.0

756.9

84.5 (357.7)

90.2 (363.4)

 

84.5 (357.7)

112C-312-3

1.0

756.9

85.4 (358.6)

89.9 (363.1)

85.4 (358.6)

Overall Means:

756.9

84.8 (358.0)

90.1 (363.3)

84.8 (358.0)

Standard Deviations:

0.0

0.5 (0.5)

0.2 (0.2)

0.5 (0.5)

CV (%):

0.00

0.61 (0.15)

0.19 (0.05)

0.61 (0.15)

1K (Kelvin) = °C + 273.15

Note:All calculations were performed using EXCEL 2010 in full precision mode.

Conclusions:
The melting point for the test substance was 84.8°C (range of 84.8 to 90.1°C) at 756.9 mm Hg.
Executive summary:

The melting point of the test substance was measured in accordance with OECD Guideline 102 and EPA OPPTS 830.7200. Subsamples of the test substance were heated in melting point capillary tubes in a temperature-controlled heating block. Measurement of melting point was limited to ≤ 400°C (approximately 673K), the maximum specified for the instrumentation used. The temperature at which fine droplets adhered uniformly to the wall of the melting point tube was accepted as the melting point. If a range of temperatures was noted between the formation of the fine droplets (beginning of melting) and transition to a liquid (end of melting), a melting range was reported. The definitive melting point test provided a mean melting point of 84.8±0.5°C (358.0K) and a mean melting range from 84.8±0.5°C (358.0K) to 90.1±0.2°C (363.3K) for the three tests. Upon melting the test substance was clear and colorless.

Description of key information

OECD Guideline 102

Key value for chemical safety assessment

Additional information

Value used for CSA:

84.8°C at 100.9 kPa