Registration Dossier
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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 223-871-0 | CAS number: 4101-68-2
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
Eyes contact : Rinse continuously with water at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin contact : Wash skin immediately with water and soap for at least 15 minutes while removing contaminated clothing.
Ingestion : Do not induce vomiting. If conscious and alert, rinse the mouth with water. Get medical aid immediately. Never give anything to drink to an unconscious person.
Inhalation : Keep the victim away from the polluted atmosphere. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid immediately.
4.2 Most important symptoms and effects both acute and delayed
No data available
4.3 Indication of any immediate medical attention and special treatment needed
No data available
Fire-fighting measures
- suitable : CO2, dry chemical powder, appropriate foam, water fog/spray
- unsuitable : jet of water
5.2 Special hazards arising from the substance or mixture
In case of fire, could form HBr and hazardous vapours.
5.3 Advice for firefighters
Wear full protective clothing and self-contained breathing apparatus. Cool containers with water fog/spray.
Accidental release measures
Evacuate the spill area of unnecessary personnel. As a precautionary measure, eliminate all ignition sources. Wear self-contained breathing apparatus and full protective clothing. Avoid contact with skin and eyes and inhalation of dust (solid) / vapours (liquid). Stop leak if possible.
6.2 Environmental precautions
Should not be released into the environment.
6.3 Method and material for containment and cleaning up
Ventilate area. Contain spillage. Sweep up spilled product (solid) without creating dust or absorb spilled product (liquid) with inert material (e.g. dry sand, vermiculite). Collect carefully in a suitable container for disposal.
Handling and storage
Handle in accordance with good industrial hygiene and safety procedures. Use adequate ventilation. Avoid inhalation of dust (solid) / vapours (liquid). Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
7.2 Conditions for safe storage, including any incompatibilities
Keep in a dry, cool, well-ventilated place. Keep away from heat, moisture, sources of ignition and incompatible substances. Store in original container. Keep container tightly closed and check periodically for leaks. Avoid stocking for too long time. The product is corrosive for most of the metals under moisture conditions.
7.3 Specific end use(s)
No data available
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
No data available
8.2 Exposure controls
Appropriate engineering controls
Use adequate ventilation. Avoid breathing vapours. Avoid contact with skin or eyes
Personal protective equipment
Respiratory protection : Necessary in case of vapours/fumes : Filter A (EN 14387) for gas and vapours of organic components with a boiling point > 65°C. In case of dust, use P3 dust masks.
Hand protection : Compatible chemical-resistant gloves.
Eyes protection : Chemical safety goggles or face shield with safety glasses.
Skin and body protection : Protective clothing and boots.
Environmental exposure controls
Should not be released into the environment
Stability and reactivity
No data available
10.2. Chemical stability
The substance is stable under normal conditions in original container.
10.3. Possibility of hazardous reactions
No data available
10.4. Conditions to avoid
Avoid contact with heat, sparks and flames. The substance is corrosive for most of the metals under moisture conditions.
10.5. Incompatible materials
Strong oxidizing agents and strong bases
10.6. Hazardous decomposition products
Under heat and moisture conditions, the substance can be decomposed and forms hydrogen bromide, carbon dioxide and carbon monoxide.
Disposal considerations
There is no uniform regulation for the disposal of chemical products and their waste in the European Union. User must ensure that this complies with all local / national laws.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.