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Diss Factsheets

Administrative data

Endpoint:
water solubility
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2010
Report date:
2010

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: Method OECD 29: Transformation / Dissolution of Metals and Metal Compounds in Aqueous media
Principles of method if other than guideline:
The analytical method associated with this test will based on ICP-MS and will be used for the determination of the total concentration of tin (Sn), lead (Pb) and other elements in the test medium.
GLP compliance:
yes
Type of method:
other: not detailed

Test material

Constituent 1
Reference substance name:
Tin ores, melting residues, hardhead
EC Number:
283-928-0
EC Name:
Tin ores, melting residues, hardhead
Cas Number:
84776-04-5
Molecular formula:
Not applicable
IUPAC Name:
Tin ores, melting residues, hardhead
Details on test material:
- Name of test material (as cited in study report): MC_BR_HARDHEAD 1002D
- Substance type: UVCB substance
- Physical state: solid
- Expiration date of the lot/batch: Not provided
- Storage condition of test material: in darkness at room temperature

Results and discussion

Water solubilityopen allclose all
Water solubility:
< 0.1 µg/L
pH:
ca. 6
Remarks on result:
other: Value representing the concentration of Sn in the test medium after 96 hours. Test duration: 7 days; Concentration of test sample: 1 mg/L load
Water solubility:
< 0.1 µg/L
pH:
ca. 6
Remarks on result:
other: Value representing the concentration of Sn in the test medium after 96 hours. Test duration: 7 days; Concentration of test sample: 10 mg/L load
Water solubility:
> 0.2 - < 0.3 µg/L
pH:
ca. 6
Remarks on result:
other: Value representing the concentration of Sn in the test medium; test solution between 96 and 168 hours. Test duration: 7 days; Concentration of test sample: 100 mg/L load
Details on results:
The total concentration of many elements was detected after 24, 96 and 168 hours at concentrations 1, 10 and 100 mg/L of test item.
Aluminium and Iron were not detectable after 24, 96 and 168 hours at the 3 concentrations.
As for Tin, it was only detectable after 96 hours at 1 and 10 mg/L load and between 24 and 168 hours at 100 mg/L load qith a concentration less than 0.3 mg/L.

Any other information on results incl. tables

Table 1: 7 days test; 1 mg/L load

Sample type

Aluminium

(AL) µg/L

Iron

(Fe) µg/L

Lead

(Pb) µg/L

Copper

(Cu) µg/L

Tin

(Sn) µg/L

Test solution after 24 hours

n.d.

n.d.

0.3

n.d.

n.d.

Test solution after 96 hours

n.d.

n.d.

0.3

0.1

0.1

Test solution after 168 hours

n.d.

n.d.

0.3

0.4

n.d.

Table 2: 7 days test; 10 mg/L load

Sample type

Aluminium

(AL) µg/L

Iron

(Fe) µg/L

Lead

(Pb) µg/L

Copper

(Cu) µg/L

Tin

(Sn) µg/L

Test solution after 24 hours

n.d.

n.d.

0.6

0.3

n.d.

Test solution after 96 hours

n.d.

n.d.

0.3

0.6

0.1

Test solution after 168 hours

n.d.

n.d.

0.3

2

n.d.

Table 3: 7 days test; 100 mg/L load

Sample type

Aluminium

(AL) µg/L

Iron

(Fe) µg/L

Lead

(Pb) µg/L

Copper

(Cu) µg/L

Tin

(Sn) µg/L

Test solution after 24 hours

n.d.

n.d.

0.1

n.d.

0.2

Test solution after 96 hours

n.d.

n.d.

n.d.

0.4

0.3

Test solution after 168 hours

n.d.

n.d.

n.d.

2

0.2

Applicant's summary and conclusion

Conclusions:
Interpretation of results (migrated information): insoluble (< 0.1 mg/L)
The test item was found higly insoluble in water as the total concentration of Sn and other elements is < 0.1 mg/L.