tert-butyl hydroperoxide

Guidance on Safe Use

First-aid measures

Product-Specific hazards and other issues :

- Corrosive, can cause severe burns to mucus membranes, gastrointestinal mucosa, skin and

 eyes. Can cause severe eye defects leading to permanent vision loss.

 Systemic poisoning with effects on CNS and blood are possible.

General advice

- Always observe self protection methods.

- Move out of dangerous area.

- Remove contaminated shoes and clothing.

- Get medical attention immediately.

- Show this material safety data sheet to the doctor in attendance.

Inhalation

- Remove to fresh air and keep at rest in a position comfortable for breathing.

- Do not leave the victim unattended.

- Keep patient warm and at rest.

- Immediately seek medical attention.

- If breathing is difficult, give oxygen.

- If unconscious place in recovery position and seek medical advice.

- In the event of unconsciousness , apnea or cardiac arrest (no Pulse) apply cardiopulmonary

 resuscitation. Do not use mouth to mouth or mouth to nose method of resuscitation, as cross

 contamination or exposure can occur to the rescuer.

Skin contact

- Immediately flush affected area with plenty of soap and water for at least 15 minutes while

 removing contaminated clothing and shoe.

- Get medical attention immediately.

Eye contact

- Immediately flush eyes with water thoroughly and continuously for 15 minutes.

- Immediately get medical attention and provide for further treatment  by an ophthalmologist due

 to possible caustic burn of the eyes. Do not stop rinsing the eyes while taking patient to hospital.

Ingestion

- Get medical attention immediately.

- Clean mouth with water and drink afterwards plenty of water.

- Do NOT induce vomiting.

- Do not give milk or alcoholic beverages.

- Never give anything by mouth to an unconscious person.

- If vomiting does occur, have victim lean forward to reduce risk of aspiration.

- Do not leave the victim unattended.

- Keep patient warm and at rest.

- If unconscious place in recovery position and seek medical advice.

- In the event of unconsciousness, apnea or cardiac arrest (no Pulse) apply cardiopulmonary

 resuscitation. Do not use mouth to mouth or mouth to nose method of resuscitation, as cross

 contamination or exposure can occur to the rescuer.

Advice to Physician :

- Treat symptomatically.  Treatment of overexposure should be directed at the control of

 symptoms and the clinical condition of the patient.  

- Can cause severe burns to mucus membranes, gastrointestinal mucosa, skin and eyes.

 Complications of ingestion include ruptured viscus, coma, seizures and cardiac arrest.

 Dermal and ocular exposures may result in severe burns with ulceration or perforation. Injury is

 possibly delayed.

 Inhalation can cause severe mucous membrane irritation and even corrosion.  Acute lung injury  

 with pulmonary edema (can be delayed) and respiratory arrest is possible.

 Systemic poisoning with acidosis, hemolysis, methemoglobin formation, shock, coma, seizures,

 disturbance of liver and kidney function  is possible.

Fire-fighting measures

Product-specific hazards and other issues :

Suitable extinguishing media

- SMALL FIRE: Use dry chemicals, CO2, water spray or alcohol-resistant foam

- LARGE FIRE: Use water spray, water fog or alcohol-resistant foam  

Unsuitable Extinguishing Media Do not use solid water stream.

Fire may produce irritating, corrosive and/or toxic gases.:

- Vapor can burn in absence of air and may be flammable at either elevated temperature or

 reduced pressure.

- Fine sprays/mists may be combustible at temperatures below normal flash point.

- Heat can cause exothermic decomposition.

- When evaporated, residual liquid will concentrate in TBHP content and may reach explosive

 level (>90%).

- Run-off may create an explosion, fire, and environmental hazard.

- Burning material may release gases, rupture closed containers, spreading fire, increasing risk of

 burns/injuries.  Availability of other combustibles may hasten burning, spreading fire.

- Flood fire area with water form a distance.

- Do not use straight streams.

- Move containers from fire area if you can do it without risk.

- Do not move cargo or vehicle if cargo has been exposed to heat.

- Fight fire from maximum distance or use unmanned hose holders or monitor  nozzles.

- Use water spray/fog for cooling.

- Always stay away from tanks engulfed in fire.

- For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw

 from area and let fire burn.

- Notify authorities immediately if liquid enters sewer/public waters.

Further information :

Special protective equipment for fire-fighters

-Do not enter fire area without proper protection.

- Wear positive pressure self-contained breathing apparatus (SCBA).

- Wear chemical protective clothing that is specifically recommended by the manufacturer. It may

 provide little or no thermal protection.

- Structural firefighters protective clothing will only provide limited protection.

Accidental release measures

Product-specific hazards and other issues

General information :

Personal precautions :

- Use personal protective equipment.

- Ensure adequate ventilation.

- Evacuate personnel to safe areas.

Methods for cleaning up

- Highly flammable liquid.

- Highly reactive material.

- Do not clean-up or dispose of, except under supervision of a specialist.

- Extinguish all ignition sources.

- Release can cause fire/explosion/health/environmental hazards.

- Liquids or vapors may ignite/react with other materials.

- Evacuate/limit access.

- Keep combustibles (wood, paper, oil, etc) away from spilled material.

- Do not touch damaged containers or spilled material unless wearing appropriate protective

 clothing.

- Keep substance wet using water spray.

- Stop leak if you can do it without risk.

- Take up small spills with inert, damp, noncombustible material using clean non-sparking tools

- and place into loosely covered plastic containers for later disposal.

- For large spills:

- Wet down with water and dike for later disposal.

- Prevent entry into waterways, sewers, basements or confined areas.

Handling and storage

Handling

Product-specific hazards and other issues

General information :

Advice on safe handling

- For industrial use only.

- Closed containers may generate internal gas pressure by decomposition (oxygen) which can

 accelerate burning of combustibles.

- Overpressure may rupture container/cause serious injury/result in or accelerate fire.

- Provide nitrogen pad to dilute any free oxygen buildup and prevent any  hydroperoxide self-

 combustion.

- Use only non-sparking tools.

- Properly ground containers before beginning transfer.

- All equipment must conform to applicable electrical code.

- Minimize formation of sprays during transfer.

- Inspect frequently to identify bulging or leaking containers.

- Isolate/depressure if safe to do so.

- Do not steam purge systems containing this material until they have been properly flushed with

 a suitable material such as mineral oil, kerosene, TBA, etc - depending on system compatibility.

 Isolate, vent, drain, wash and purge systems or equipment before maintenance or repair.

- Extinguish all ignition sources.

- Check atmosphere for explosiveness and oxygen deficiencies.

- Wear recommended personal protective equipment.

- Observe precautions pertaining to confined space entry.

Advice on protection against fire and explosion

- Avoid formation of aerosol.

- Keep away from sources of ignition - No smoking.

- Take measures to prevent the build up of electrostatic charge.

- Keep away from combustible material.

Storage

Requirements for storage areas and containers : - Keep away from open flames, hot surfaces and sources of ignition.

- Keep away from reducing agents.

- Protect from contamination.

- Store so fire extinguishing media can be applied to all containers from a safe distance/protected

 location.

- Store between 50-100°F (10-38°C).

Recommended and Unsuitable Materials for Storage :

Container Advice : Stainless steel

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3109

Shipping information

Proper shipping name and description:

ORGANIC PEROXIDE TYPE F, LIQUID

Chemical name:

TERT-BUTYL HYDROPEROXIDE <=70% IN WATER

Language:

English

Labels:

5.2 (8)

Special provisions / remarks

Special provisions:

Hazard Identification Number : 539

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3109

Shipping information

Proper shipping name and description:

ORGANIC PEROXIDE TYPE F, LIQUID

Chemical name:

TERT-BUTYL HYDROPEROXIDE <=70% IN WATER

Language:

English

Labels:

5.2 (8)

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

3109

Shipping information

Proper shipping name and description:

ORGANIC PEROXIDE TYPE F, LIQUID (TERT-BUTYL HYDROPEROXIDE <=70% IN WATER)

Chemical name:

tert-butyl hydroperoxide

Labels:

5.2 (8)

Marine pollutant

Special provisions / remarks

Remarks:

TERT-BUTYL HYDROPEROXIDE <=70% IN WATER
Toxic to the Aquatic Environment Mark Required

Air transport (UN RTDG/ICAO/IATA)

Shipping

Special provisions / remarks

Remarks:

Not Supported
If transportation information is required, please contact Logistics Compliance at: [e-mail]

SpecialProvisions

Exposure controls / personal protection

Engineering measures :

- Electrical equipment should be grounded and conform to applicable electrical code.  Provide

 local exhaust or general room ventilation to minimize exposure to vapors.  Both local exhaust

 and good general room ventilation must be provided not only to control exposure but also to

 prevent formation of flammable mixtures.  

Personal protective equipment

Respiratory protection

In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:

use respiratory equipment conforming to EN140 with suitable filter (filter type A) or wear a self contained respiratory apparatus

Hand protection

Chemical-resistant protective gloves (EN 374) for example, butyl rubber (Butyl) gloves; Material thickness 0.5 mm, Break through time >= 480 min.  Source: GESTIS substance database (hazardous substance information system of commercial professional associations)

Suitability for specific workplaces should be clarified with protective glove manufacturers.

Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Before removing gloves clean them with soap and water.

Selection of appropriate personal protective equipment should be based on an evaluation of the performance characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of use, and the hazards and/or potential hazards that may be encountered during use.

Eye protection

- Eye protection, including both chemical splash goggles and face shield, must be worn when

 possibility exists for eye contact due to splashing/spraying liquid, airborne particles, or vapor.

Skin and body protection

- Choose body protection according to the amount and concentration of the dangerous substance

 at the work place

- Use PPE that is chemical resistant to the product and prevents skin contact.

- Fire retardant clothing is appropriate for routine occupational use.

- The equipment must be cleaned thoroughly after each use.

Hygiene measures

- Selection of appropriate personal protective equipment should be based on an evaluation of the

 performance characteristics of the protective equipment relative to the task(s) to be performed,

 conditions present, duration of use, and the hazards and/or potential hazards that may be

 encountered during use.

- Emergency eye wash fountains and safety showers should be available in the immediate vicinity

 of any potential exposure.

- Use good personal hygiene practices.

 Wash hands before eating, drinking, smoking, or using toilet facilities.

 Take off contaminated clothing and wash before reuse.

- Avoid contact with skin, eyes and clothing.

- When using do not eat or drink.

- When using do not smoke.

- Wash hands before breaks and immediately after handling the product.

Environmental exposure controls

General advice

- Do not flush into surface water or sanitary sewer system.

- Prevent further leakage or spillage if safe to do so.

- If the product contaminates rivers and lakes or drains inform respective authorities.

Stability and reactivity

Chemical stability

- Stable under recommended storage conditions.

Possibility of hazardous reactions

- Hazardous reactions   :  Not expected to occur.

                                             Vapors may form explosive mixture with air.

Conditions to avoid

- Conditions to avoid   : Prolonged exposure to heat, fire, or any conditions which would concentrate the liquid.

Incompatible materials  

- Materials to avoid :  Metal compounds.

                                     Oxidizable materials.

                                     Reducing agents.

                                     Sulfur compounds.

                                     Ketones.

Hazardous decomposition products

- Hazardous decomposition products : Not expected to decompose under normal conditions

- Thermal decomposition :  Thermal decomposition may produce carbon monoxide and other toxic vapors.

                                                 High temperatures/chemical contamination can liberate gaseous oxygen causing hazardous pressure build-up.

                                                 Incomplete combustion can result in the production of carbon monoxide, carbon dioxide and other toxic gases.

Disposal considerations

Product :

- Contaminated product, soil or water containing undecomposed reactive components may be  hazardous waste.

- Landfill solids at permitted sites.

- Use registered transporters.

- Concentrated liquid waste may be reacted harmlessly by combining with dilute (less than 10%)   sodium bisulfite (reducing agent) and alkali solution/mixing thoroughly until reaction heat  dissipates.

- Resulting solution may be biologically treatable.

- Assure effluent complies with applicable regulations.

- The product should not be allowed to enter drains, water courses or the soil.

- Do not contaminate ponds, waterways or ditches with chemical or used container.

Contaminated packaging :

- Empty remaining contents.

- Dispose of as unused product.

- Do not re-use empty containers.

- Do not burn, or use a cutting torch on, the empty drum.