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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Other distribution data

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Administrative data

Endpoint:
other distribution data
Type of information:
calculation (if not (Q)SAR)
Adequacy of study:
supporting study
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
documentation insufficient for assessment
Remarks:
Limited information available

Data source

Referenceopen allclose all

Reference Type:
study report
Title:
Unnamed
Year:
1981
Reference Type:
review article or handbook
Title:
Handbook of Environmental Fate and Exposure Data for Organic Chemicals.
Author:
Howard, P.H.
Year:
1993
Bibliographic source:
Volume IV. Solvents 2. Lewis Publishers, London.
Reference Type:
other company data
Title:
Unnamed
Year:
1992

Materials and methods

Principles of method if other than guideline:
No information available
GLP compliance:
not specified
Type of study:
volatility
Media:
water - air

Test material

Constituent 1
Chemical structure
Reference substance name:
Acetonitrile
EC Number:
200-835-2
EC Name:
Acetonitrile
Cas Number:
75-05-8
Molecular formula:
C2H3N
IUPAC Name:
acetonitrile
Test material form:
liquid

Results and discussion

Any other information on results incl. tables

Based on the value of Henry's Law Constant (2.6 x 10-5 m3 atm/mole) volatilization is probably significant for surface water, although the rate may be slow. A volatilization half-life of 21 hours would be predicted for a 1 m deep river flowing at 1 m/sec, if the wind speed was 3 m/sec. Volatilization would become particularly important as a loss process in shallow waters (Howard, 1993; IPCS, 1992). Volatilization half-lives (first order kinetics) have been predicted from Henry's Law Constant using the EXAMS computer simulation: pond water 11 days river water 6 days oligotrophic lake 34 days eutrophic lake 36 days (Burns et al. 1981).

Volatilization half-lives (first order kinetics) have been predicted from Henry's Law Constant using the EXAMS computer

simulation:

       pond water         11 days

       river water        6 days

       oligotrophic lake  34 days

       eutrophic lake     36 days

                           (Burns et al. 1981).

Applicant's summary and conclusion

Executive summary:

Based on the value of Henry's Law Constant (2.6 x 10-5 m3 atm/mole) volatilization is probably significant for surface water, although the rate may be slow. A volatilization half-life of 21 hours would be predicted for a 1 m deep river flowing at 1 m/sec, if the wind speed was 3 m/sec. Volatilization would become particularly important as a loss process in shallow waters (Howard, 1993; IPCS, 1992). Volatilization half-lives (first order kinetics) have been predicted from Henry's Law Constant using the EXAMS computer simulation: pond water 11 days river water 6 days oligotrophic lake 34 days eutrophic lake 36 days (Burns et al. 1981).