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Diss Factsheets
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EC number: 232-445-3 | CAS number: 8030-70-4
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
![](https://poisoncentres.echa.europa.eu/o/diss-blank-theme/images/factsheets/A-REACH/factsheet/print_physical-and-chemical-properties.png)
Flammability
Administrative data
Link to relevant study record(s)
- Endpoint:
- substances / mixtures which in contact with water emit flammable gases
- Data waiving:
- study scientifically not necessary / other information available
- Justification for data waiving:
- the study does not need to be conducted because the substance is known to be soluble in water to form a stable mixture
- Endpoint:
- flammable solids
- Data waiving:
- study scientifically not necessary / other information available
- Justification for data waiving:
- other:
- Endpoint:
- flammable solids
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Study period:
- 2012-11-30
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.10 (Flammability (Solids))
- Version / remarks:
- , 2008
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- other: Recommendations on the TRANSPORT OF DANGEROUS GOODS: Manual of Tests and Criteria, 5th edition, New York and Geneva, 2009: Class 4, Division 4.1: Readily Combustible Solids, Test N.1
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- other: VDI 2263, sheet 1
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
- Remarks:
- signed, 2010-08-25
- Test procedure:
- burning rate test: preliminary screening test
- Burning time:
- 555 s
- Remarks on result:
- other: over a distance of 200 mm in the preliminary test
- Interpretation of results:
- not classified based on GHS criteria
- Conclusions:
- The test item could be ignited applying a flame as ignition source. The test item burned over a distance of 200 cm within 9 min and 15 s. The product neither has to be classified as highly flammable solid according to Directive 67/548/EEC, nor as readily combustible solid in class 4.1 according to the UN-Transport regulation and nor as flammable solid according to Regulation EC 1272/2008 (CLP).
- Endpoint:
- flammable solids
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Study period:
- 2012-11-30
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.10 (Flammability (Solids))
- Version / remarks:
- , 2008
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- other: Recommendations on the TRANSPORT OF DANGEROUS GOODS: Manual of Tests and Criteria, 5th edition, New York and Geneva, 2009: Class 4, Division 4.1: Readily Combustible Solids, Test N.1
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- other: VDI 2263, sheet
- Deviations:
- no
- GLP compliance:
- no
- Test procedure:
- burning time (test type not further specified)
- Burning time:
- ca. 3 s
- Remarks on result:
- other: the test item showed a local burning, which ended after a few seconds
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- The test item Fatty acids, tall-oil, calcium salts could be ignited applying a flame as ignition source. The test item showed a local burning, which ended after a few seconds. The product neither has to be classified as highly flammable solid according to Directive 67/548/EEC, nor as readily combustible solid in class 4.1 according to the UN-Transport regulation and nor as flammable solid according to Regulation EC 1272/2008 (CLP).
- Endpoint:
- pyrophoric solids
- Data waiving:
- study scientifically not necessary / other information available
- Justification for data waiving:
- the study does not need to be conducted because the substance is known to be stable in contact with air at room temperature for prolonged periods of time (days) and hence, the classification procedure does not need to be applied
Referenceopen allclose all
Preliminary Test
The test item could be ignited at room temperature using a propane burner flame as ignition source. The test item burned over a distance of 200 cm within 9 min and 15 s min. Therefore, the main test had not to be performed.
Classification
Directive 67/548/EEC
The product does not have to be classified as highly flammable solid with the danger symbol F according to Directive 67/548/EEC.
UN-Transport regulations
The product does not have to be classified as readily combustible solid in Class 4 Division 4.1 according to the UN-Transport Regulations.
Regulation EC 1272/2008 (CLP Regulation)
The product does not have to be classified as flammable solid according to Regulation EC 1272/2008 (CLP Regulation) Annex 1: 2.7.
Preliminary Test
The test item could be ignited at room temperature using a propane burner flame as ignition source. The test item showed a local burning, which ended after a few seconds. Therefore, the main test had not to be performed.
Classification
Directive 67/548/EEC
The product does not have to be classified as highly flammable solid with the danger symbol F according to Directive 67/548/EEC.
UN-Transport regulations
The product does not have to be classified as readily combustible solid in Class 4 Division 4.1 according to the UN-Transport Regulations.
Regulation EC 1272/2008 (CLP Regulation)
The product does not have to be classified as flammable solid according to Regulation EC 1272/2008 (CLP Regulation) Annex 1: 2.7.
Description of key information
Testing of flammability does not appear scientifically necessary according to Regulation (EC) No 1907/2006, Annex XI, Section 1.
- Testing of flammability of solids (A.10) and gases (A.11) is not considered to be required, since flammability tests with two metal carboxylates did not show flammable properties, based on this fact and based on the stable oxidation state of the manganese cation, fatty acids, tall-oil, manganese salts can be designated as non-flammable.
- Testing for flammability in contact with water (A.12) is not considered to be required, because fatty acids, tall-oil, manganese salts does not contain groups that might lead to a reaction with water or damp air, leading to the development of dangerous amounts of gas or gases which may be highly flammable
- Testing of pyrophoric properties of solids and liquids (A.13) is not considered to be required, since fatty acids, tall-oil, manganese salts is stable at ambient temperature. It does not contain any chemical group that might lead to spontaneous ignition a short time after coming in contact with air at room temperature (approx. 20 °C)
Key value for chemical safety assessment
- Flammability:
- not classified
Additional information
Flammability
In accordance with Regulation (EC) No 1907/2006, Annex XI, Section 1, testing of flammability is not considered to be required for fatty acids, tall-oil, manganese salts as it is an inorganic, highly viscous, sticky, brown substance whereas the manganese cation is in the stable (II+) oxidation state and the anion of an acid which is not susceptible to any form of oxidation as it is the fact for manganese bis(2-ethylhexanoate) and fatty acids, tall-oil, calcium salts, respectively. For both substances tests on flammability are available (see supporting information – IUCLID section 4.13). Fatty acids, tall-oil, manganese salts can thus be designated as non-flammable (Guidance on information requirements and chemical safety assessment Chapter R.7a: Endpoint specific guidance, section R.7.1.10.3). In addition, long-term industrial experience in handling indicates that fatty acids, tall-oil, manganese salts is not flammable.
Pyrophoric properties
Testing for pyrophoric properties of liquids is not considered to be required, since fatty acids, tall-oil, manganese salts is stable at ambient temperature. It does not contain any chemical groups that might lead to spontaneous ignition a short time after coming in contact with air at room temperature (ca. 20 °C) . Furthermore, long-term industrial experience in handling shows that fatty acids, tall-oil, manganese salts does not ignite in contact with air (in accordance with Regulation (EC) No 1907/2006, Annex XI, Section 1).
Flammability in contact with water
Testing for flammability in contact with water is not considered to be required, because fatty acids, tall-oil, manganese salts does not contain groups that might lead to a reaction with water or damp air, leading to the development of dangerous amounts of gas or gases which may be highly flammable. Furthermore, long-term industrial experience in practical handling of fatty acids, tall-oil, manganese salts shows that it does not react with water, and recent experimental testing for water solubility has also not reported any formation of gases (in accordance with Regulation (EC) No 1907/2006, Annex XI, Section 1.2).
Justification for classification or non-classification
Fatty acids, tall-oil, manganese salts does not need to be classified according to CLP Regulation (EC) No 1272/2008 since it is not highly flammable.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
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