Registration Dossier
Registration Dossier
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EC number: 214-778-6 | CAS number: 1193-72-2
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
Description of first aid measures
General Advice:
In case of exposure seek medical advice.
If person is unconscious and breathing place in recovery position.
If person is not breathing give artificial respiration and immediately seek medical advice.
In the event of exposure by inhalation:
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Immediately seek medical advice.
In the event of splashes or contact with eyes:
Rinse cautiously with fresh, clean water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing with
water for 15 minutes holding the eyelids open.
If there is any redness, pain or visual impairment seek medical attention.
In the event of splashes or contact with skin:
Remove contaminated clothing and wash the skin thoroughly with soap and water.
Watch out for any remaining product between skin and clothing, watches, shoes, etc.
If the contamination is to a large area and/or there is damage to the skin, seek medical advice immediately.
In the event of swallowing:
Seek medical advice immediately. Show the label.
Do not induce vomiting.
Do not give the patient anything orally.
If the quantity is small (no more than one mouthful), rinse the mouth with water and seek medical advice.
General Advice:
In case of exposure seek medical advice.
If person is unconscious and breathing place in recovery position.
If person is not breathing give artificial respiration and immediately seek medical advice.
In the event of exposure by inhalation:
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Immediately seek medical advice.
In the event of splashes or contact with eyes:
Rinse cautiously with fresh, clean water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing with
water for 15 minutes holding the eyelids open.
If there is any redness, pain or visual impairment seek medical attention.
In the event of splashes or contact with skin:
Remove contaminated clothing and wash the skin thoroughly with soap and water.
Watch out for any remaining product between skin and clothing, watches, shoes, etc.
If the contamination is to a large area and/or there is damage to the skin, seek medical advice immediately.
In the event of swallowing:
Seek medical advice immediately. Show the label.
Do not induce vomiting.
Do not give the patient anything orally.
If the quantity is small (no more than one mouthful), rinse the mouth with water and seek medical advice.
Fire-fighting measures
1. Extinguishing media
Suitable methods of extinction
In the event of a fire, use:
Water spray, alcohol-resistant foam, dry chemical or CO2 extinguisher.
Unsuitable methods of extinction
In the event of a fire, do not use:
None.
2 Special hazards arising from the substance or mixture
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Do not breathe in smoke.
In the event of a fire, the following may be formed:
- Carbon monoxide (CO)
- Carbon dioxide (CO2)
- Hydrogen chloride (HCl)
- Hydrogen bromide (HBr)
3 Advice for firefighters
Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel are to be equipped with
breathing apparatus.
Use water to cool unopened containers.
Suitable methods of extinction
In the event of a fire, use:
Water spray, alcohol-resistant foam, dry chemical or CO2 extinguisher.
Unsuitable methods of extinction
In the event of a fire, do not use:
None.
2 Special hazards arising from the substance or mixture
A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.
Do not breathe in smoke.
In the event of a fire, the following may be formed:
- Carbon monoxide (CO)
- Carbon dioxide (CO2)
- Hydrogen chloride (HCl)
- Hydrogen bromide (HBr)
3 Advice for firefighters
Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel are to be equipped with
breathing apparatus.
Use water to cool unopened containers.
Accidental release measures
1. Personal precautions, protective equipment and emergency procedures
Consult the safety measures listed under sections " Handling and storage" and Exposure controls / personal protection"
For non- emergency personnel
Use personal protective equipment.
Avoid any contact with the skin and eyes. Avoid breathing vapours, mist or gas.
If a large quantity has been spilt, evacuate all personnel and only allow intervention by trained operators equipped with safety
equipment.
For emergency responders
Emergency responders must use suitable personal protective equipment.
2. Environmental precautions
Prevent any material from entering drains or waterways. Discharge into the environment must be avoided.
3. Methods and material for containment and cleaning up
Pick up without creating dust. Keep in suitable closed containers for disposal according to local regulations
Consult the safety measures listed under sections " Handling and storage" and Exposure controls / personal protection"
For non- emergency personnel
Use personal protective equipment.
Avoid any contact with the skin and eyes. Avoid breathing vapours, mist or gas.
If a large quantity has been spilt, evacuate all personnel and only allow intervention by trained operators equipped with safety
equipment.
For emergency responders
Emergency responders must use suitable personal protective equipment.
2. Environmental precautions
Prevent any material from entering drains or waterways. Discharge into the environment must be avoided.
3. Methods and material for containment and cleaning up
Pick up without creating dust. Keep in suitable closed containers for disposal according to local regulations
Handling and storage
Requirements relating to storage premises apply to all facilities where the substance is handled.
1. Precautions for safe handling
Avoid contact with skin and eyes. Always wash hands after handling.
Remove and wash contaminated clothing before re-using. Avoid inhalation of vapour or mist.
Do not allow material to enter drains or waterways.
Fire prevention
Handle in well-ventilated areas.
Keep away from sources of ignition. Take measures to prevent the build-up of electrostatic charge.
Prevent access by unauthorised personnel.
Recommended equipment and procedures
For personal protection, see Section "Exposure controls/ personal protection"
Observe precautions stated on label and also industrial safety regulations. Ensure adequate ventilation, especially in confined areas.
Also provide respirators for emergency interventions.
Prohibited equipment and procedures
No smoking, eating or drinking in areas where the substance is used.
2.Conditions for safe storage, including any incompatibilities
Storage
Keep the container tightly closed in a cool, dry, well-ventilated place.
Keep away from food and drink, including those for animals.
Packaging
Always keep in packaging made of an identical material to the original.
1. Precautions for safe handling
Avoid contact with skin and eyes. Always wash hands after handling.
Remove and wash contaminated clothing before re-using. Avoid inhalation of vapour or mist.
Do not allow material to enter drains or waterways.
Fire prevention
Handle in well-ventilated areas.
Keep away from sources of ignition. Take measures to prevent the build-up of electrostatic charge.
Prevent access by unauthorised personnel.
Recommended equipment and procedures
For personal protection, see Section "Exposure controls/ personal protection"
Observe precautions stated on label and also industrial safety regulations. Ensure adequate ventilation, especially in confined areas.
Also provide respirators for emergency interventions.
Prohibited equipment and procedures
No smoking, eating or drinking in areas where the substance is used.
2.Conditions for safe storage, including any incompatibilities
Storage
Keep the container tightly closed in a cool, dry, well-ventilated place.
Keep away from food and drink, including those for animals.
Packaging
Always keep in packaging made of an identical material to the original.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- no
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Marine transport (UN RTDG/IMDG)
- UN number:
- no
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- no
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Additional transport information
Additional information
- Special provisions / remarks / other:
- Exempt from transport classification and labelling
Exposure controls / personal protection
1. Control parameters
Contains no substances with occupational exposure limit values.
2. Exposure controls
Handle in accordance with good industrial hygiene and safety practice. Ensure that there is adequate ventilation, especially in confined
areas. Never eat, drink or smoke during use. Wash hands before breaks and at the end of workday.
Personal protection measures, such as personal protective equipment
Pictogram(s) indicating the obligation of wearing personal protective equipment (PPE): protective gloves, protective glasses; protective clothes,
protective mask
Use personal protective equipment that is clean and has been properly maintained. Store personal protective equipment in a clean place,
away from the work area. Remove and wash contaminated clothing before re-using
Eye / face protection
Avoid contact with eyes.
Wear mask goggles in accordance with standard EN166.
Provide eyewash stations in facilities where the product is handled constantly.
Hand protection
Avoid skin contact.
Use suitable protective gloves that are resistant to chemical agents in accordance with EU Directive 89/686/EEC and standard EN374.
Gloves must be selected according to the application and duration of use at the workstation in question: other chemical products that may be handled,
necessary physical protection (cutting, pricking, heat protection), level of dexterity required.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
Body protection
Avoid skin contact.
Wear suitable impervious protective clothing selected according to the concentration and amount of the substance at the specific
workstation.
Work clothing worn by personnel shall be laundered regularly.
Respiratory protection
Avoid breathing vapours or mist.
If the ventilation is insufficient, wear appropriate breathing apparatus.
Where air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN14387)
respirator cartridges as a backup to standard exposure controls. If the respirator is the sole means of protection,
use a full-face supplied air respirator.
Contains no substances with occupational exposure limit values.
2. Exposure controls
Handle in accordance with good industrial hygiene and safety practice. Ensure that there is adequate ventilation, especially in confined
areas. Never eat, drink or smoke during use. Wash hands before breaks and at the end of workday.
Personal protection measures, such as personal protective equipment
Pictogram(s) indicating the obligation of wearing personal protective equipment (PPE): protective gloves, protective glasses; protective clothes,
protective mask
Use personal protective equipment that is clean and has been properly maintained. Store personal protective equipment in a clean place,
away from the work area. Remove and wash contaminated clothing before re-using
Eye / face protection
Avoid contact with eyes.
Wear mask goggles in accordance with standard EN166.
Provide eyewash stations in facilities where the product is handled constantly.
Hand protection
Avoid skin contact.
Use suitable protective gloves that are resistant to chemical agents in accordance with EU Directive 89/686/EEC and standard EN374.
Gloves must be selected according to the application and duration of use at the workstation in question: other chemical products that may be handled,
necessary physical protection (cutting, pricking, heat protection), level of dexterity required.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
Body protection
Avoid skin contact.
Wear suitable impervious protective clothing selected according to the concentration and amount of the substance at the specific
workstation.
Work clothing worn by personnel shall be laundered regularly.
Respiratory protection
Avoid breathing vapours or mist.
If the ventilation is insufficient, wear appropriate breathing apparatus.
Where air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN14387)
respirator cartridges as a backup to standard exposure controls. If the respirator is the sole means of protection,
use a full-face supplied air respirator.
Stability and reactivity
1. Reactivity
The product is stable under normal conditions of use.
2. Chemical stability
This substance is stable under the recommended handling and storage conditions in Section 7.
3. Possibility of hazardous reactions
No data available
4. Conditions to avoid
Heat, flames and sparks.
5. Incompatible materials
Keep away from strong oxidising materials.
6. Hazardous decomposition products
The thermal decomposition may release / form:
- Carbon monoxide (CO)
- Carbon dioxide (CO2)
- Hydrogen chloride (HCl)
- Hydrogen bromide (HBr)
The product is stable under normal conditions of use.
2. Chemical stability
This substance is stable under the recommended handling and storage conditions in Section 7.
3. Possibility of hazardous reactions
No data available
4. Conditions to avoid
Heat, flames and sparks.
5. Incompatible materials
Keep away from strong oxidising materials.
6. Hazardous decomposition products
The thermal decomposition may release / form:
- Carbon monoxide (CO)
- Carbon dioxide (CO2)
- Hydrogen chloride (HCl)
- Hydrogen bromide (HBr)
Disposal considerations
Proper waste management of the substance and/or its container must be determined in accordance with Directive 2008/98/EC.
1. Waste treatment methods
Contact a licensed professional waste disposal service to dispose of this material. Offer surplus and non-recyclable solutions to a
licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped
with an afterburner and scrubber.
Waste:
Waste management must be carried out without endangering human health, without harming the environment and, in particular,
without risk to water, air, soil, plants or animals.
Recycle or dispose of waste in compliance with current legislation via a certified collector or company.
Do not contaminate the ground or water with waste, do not dispose of waste into the environment.
Contaminated packaging:
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor
1. Waste treatment methods
Contact a licensed professional waste disposal service to dispose of this material. Offer surplus and non-recyclable solutions to a
licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped
with an afterburner and scrubber.
Waste:
Waste management must be carried out without endangering human health, without harming the environment and, in particular,
without risk to water, air, soil, plants or animals.
Recycle or dispose of waste in compliance with current legislation via a certified collector or company.
Do not contaminate the ground or water with waste, do not dispose of waste into the environment.
Contaminated packaging:
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
