Registration Dossier
Registration Dossier
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EC number: 203-820-9 | CAS number: 110-97-4
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Remove contaminated clothing.
If inhaled: Keep patient calm, remove to fresh air, seek medical attention
On skin contact: Wash thoroughly with soap and water.
On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye
specialist.
On ingestion: Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: Overexposure may cause:, abdominal cramps, shortness of breath, coughing
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Remove contaminated clothing.
If inhaled: Keep patient calm, remove to fresh air, seek medical attention
On skin contact: Wash thoroughly with soap and water.
On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye
specialist.
On ingestion: Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: Overexposure may cause:, abdominal cramps, shortness of breath, coughing
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: water spray, dry powder, carbon dioxide, alcohol-resistant foam
Special hazards arising from the substance or mixture nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
Advice for fire-fighters
Special protective equipment: Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Suitable extinguishing media: water spray, dry powder, carbon dioxide, alcohol-resistant foam
Special hazards arising from the substance or mixture nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
Advice for fire-fighters
Special protective equipment: Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr). Dispose of absorbed material in accordance with regulations
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr). Dispose of absorbed material in accordance with regulations
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.
Precautions for safe handling
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should
be kept handy.
Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Storage stability:
Storage temperature: 20 °C
Storage duration: 24 Months
May yellow after lengthy storage.
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
If stored below the limit temperature precipitation or gelatinization of product is possible. This process is reversible.
Precautions for safe handling
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should
be kept handy.
Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Storage stability:
Storage temperature: 20 °C
Storage duration: 24 Months
May yellow after lengthy storage.
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
If stored below the limit temperature precipitation or gelatinization of product is possible. This process is reversible.
Transport information
Land transport (UN RTDG/ADR/RID)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as a dangerous good under transport regulations.
Inland waterway transport (UN RTDG/ADN(R))
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as a dangerous good under transport regulations.
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not classified as a dangerous good under transport regulations.
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site. Written confirmation of application of Strictly Controlled Conditions has been received from affected Distributor and Downstream Manufacturer/User of the Registrant's intermediate.
Components with workplace control parameters
The substances without values are not listed in the occupational exposure regulations for the validity
area of this safety data sheet.
PNEC
freshwater: 0.2777 mg/l
marine water: 0.02777 mg/l
intermittent release: 2.777 mg/l
sediment (freshwater): 2.19 mg/kg
sediment (marine water): 0.219 mg/kg
soil: 0.275 mg/kg
STP: 15000 mg/l
DNEL
worker: Long-term exposure- systemic effects, dermal: 12.5 mg/kg
consumer: Long-term exposure- systemic effects, dermal: 6.3 mg/kg
worker: Long-term exposure- systemic effects, Inhalation: 16 mg/m3
consumer: Long-term exposure- systemic effects, Inhalation: 3.9 mg/m3
consumer: Long-term exposure- systemic effects, oral: 1.3 mg/m3
Exposure controls
Personal protective equipment
Respiratory protection: Respiratory protection in case of vapour/aerosol release.
Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment
Components with workplace control parameters
The substances without values are not listed in the occupational exposure regulations for the validity
area of this safety data sheet.
PNEC
freshwater: 0.2777 mg/l
marine water: 0.02777 mg/l
intermittent release: 2.777 mg/l
sediment (freshwater): 2.19 mg/kg
sediment (marine water): 0.219 mg/kg
soil: 0.275 mg/kg
STP: 15000 mg/l
DNEL
worker: Long-term exposure- systemic effects, dermal: 12.5 mg/kg
consumer: Long-term exposure- systemic effects, dermal: 6.3 mg/kg
worker: Long-term exposure- systemic effects, Inhalation: 16 mg/m3
consumer: Long-term exposure- systemic effects, Inhalation: 3.9 mg/m3
consumer: Long-term exposure- systemic effects, oral: 1.3 mg/m3
Exposure controls
Personal protective equipment
Respiratory protection: Respiratory protection in case of vapour/aerosol release.
Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Eye protection: Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment
Stability and reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Reacts with acid chlorides. Reacts with acids. Incompatible with acid chlorides and acid anhydrides.
Reacts with halogenated compounds. Reacts with oxidizing agents. Reacts with isocyanates. The progress of reaction is exothermic.
Conditions to avoid
Avoid extreme temperatures.
Incompatible materials
Substances to avoid: acid chlorides, acid anhydrides, acid forming substances, acids, isocyanates, oxidizing agents
Hazardous decomposition products
Thermal decomposition products: carbon oxides, nitrogen oxides
No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Reacts with acid chlorides. Reacts with acids. Incompatible with acid chlorides and acid anhydrides.
Reacts with halogenated compounds. Reacts with oxidizing agents. Reacts with isocyanates. The progress of reaction is exothermic.
Conditions to avoid
Avoid extreme temperatures.
Incompatible materials
Substances to avoid: acid chlorides, acid anhydrides, acid forming substances, acids, isocyanates, oxidizing agents
Hazardous decomposition products
Thermal decomposition products: carbon oxides, nitrogen oxides
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
