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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
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EC number: 701-017-2 | CAS number: -
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Administrative data
First-aid measures
General Advice:
First-aid responders should wear protective gloves and in case of spillages respiratory protection. Remove victims from danger zone. Remove contaminated clothing immediately and dispose them off.
If inhaled:
Keep patient calm, remove to fresh air, seek medical advice.
On skin contact:
Wipe of, wash immediately with polyethylene glycol if available, followed by plenty of water. Consult a medical doctor in case of skin irritation persists.
On contact with eyes:
Immeadiately wash affected eyes with plenty of lukewarm water (at least 10 minutes) with eyelids held open. Consult eye specialist.
If swallowed:
Immediately rinse mouth with water, do not induce vomiting, seek medical attention.
Note to the physician:
Product irritates the respiratory system and is a potential trigger for skin and respiratory system sensitization. the therapy of the acute irritation and bronchial stenosis is primarily symptomatical. Depending on the extent of exposure and the severity of symptoms, a long term medical attendance might become necessary.
Fire-fighting measures
Suitable extinguishing media:
dry extinguishng media, carbon dioxide, foam, water spray
unsuitable: full water jet
During fire, carbon dioxid, carbon monoxid, nitrogen oxides, isocyanate vapours and traces of hydrogen cyanide might evolve. Do not breath fumes.
During a surrounding fire buildup of pressure possible. Danger of bursting. Cool containers and remove them if possible out of the danger area.
During fire fighting respiratory protection with independend air supply and sealed, chemical resistant inherent body protection required.
Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Accidental release measures
Personal precautions:
Personal precautions: No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Put on appropriate personal protective equipment
Environmental precautions:
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Cleaning methods:
Remove mechanically. Cover residual amounts with absorbent material (e.g. sand, saw dust, chemical absorbers made of calcium silicate) for 1 hour and dispose off the material. Do not seal waste containers (CO2 evolution). Keep humid outdoors on a secure area.
Handling and storage
Handling:
Provide suitable exhaust ventilation at the processing machines. Ensure thorough ventilation of stores and work area. Avoid aerosol formation. Wear respiratory protection when handling heated product or while spraying. Protect against moisture. Danger of bursting if contaminated with water and sealed gastight. Products freshly manufactured from isocyanates can contain incompletely reacted isocyanates and other dangerous substances. Completely cured polyurethanes (24 h after production) can generally be handled without PPE. Avoid the contact with skin and eyes as well as the breathing of vapours.
Storage:
Store in dry, well-ventilated store-room in tightly closed drums and containers. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2078
Shipping information
- Proper shipping name and description:
- TOLUENDIISOCYANAT
- Chemical name:
- Desmodur VP.PU 60WF14
- Language:
- English
- Labels:
- 6.1
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2078
Shipping information
- Proper shipping name and description:
- TOLUENDIISOCYANAT
- Chemical name:
- Desmodur VP.PU 60WF14
- Language:
- English
- Labels:
- 6.1
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 2078
Shipping information
- Proper shipping name and description:
- TOLUENE DIISOCYANATE
- Chemical name:
- Desmodur VP.PU 60WF14
- Labels:
- 6.1
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2078
Shipping information
- Proper shipping name and description:
- TOLUENE DIISOCYANATE
- Chemical name:
- Desmodur VP.PU 60WF14
- Labels:
- 6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Components with workplace control parameters:
CAS-No.: 91-08-7: toluene-2,6-diisocyanate.
MK value (max. concentration): 0,035 mg/m3
CAS-No.: 584-84-9: 4-methyl-m-phenylene diisocyanate
MK value (max. concentration): 0,035 mg/m3
Personal protective equipment:
respiratory protection:
In case of unsuficient ventilation or spray application, respiratory protection equipment is stipulated. filter for organic gases with particle filter, at least A2P2 (EN 143 or 149)
hand protection:
Chemical resistant protective gloves (EN 374).
Suitable materials also with prolonged, direct contact (recommended: protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
fluoro rubber (FBR) - 0.4 mm coating thickness
butyl rubber (butyl) - 0.7 mm coating thickness
recommendation: dispose contaminated gloves off
Eye protection:
Safety glasses with side-shieleds (frame goggles) (e.g. EN 166), face shield
Body protection:
wear suitable protective clothings
General safety and hygiene measures:
Do not breath vapours/spray. With products freshly manufatured from isocyanates body protection and chemical resistant protective gloves is recommended. Wearing of closed work clothing is required and additionally to the stated personal protective equipent. Keep away from drink, food and animal feeding stuffs. No eating, drinking, smoking or tobacco use at the place of work. Take off immediately all contaminated clothing. Hands and face should be washed before breaks and at the end of shift. At the end of the shift the skin should be cleaned and skin-care agents applied.
Stability and reactivity
Dangerios reactions: exothermic reactions with amines and alcoholes, CO2 evolution on contact with water, in sealed containers increase of pressure, danger of bursting
Thermal decomposition: 200 °C (polymerisation, CO2 evolution)
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
Disposal considerations
Product residues anduncleaned empty containers should be packaged, sealed, labelled, and disposed of or recycled according to relevant national and local regulations. For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used.
ncinerate in suitable incineration plant, observing local authority regulations.
This product and any uncleaned containers must be disposed of as hazardous waste.
Waste key: 08 05 01
Contaminated packaging:
contaminated packaging should be emptied as far as possible; than it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.