2-methyl-p-phenylenediamine

Guidance on Safe Use

First-aid measures

Description of first-aid measuresGeneral informationIn case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).After inhalationRemove victim to fresh air and allow to rest. Seek medical advice.After contact with skinWash immediately with plenty of water. If inflammation or irritation persists, seek medical advice.After contact with eyesRinse immediately and abundantly with water by prising open the eyelids, for at least 15 minutes. Seek medical treatment by eye specialist.After ingestionCall medical assistance immediately and show a copy of the material safety data sheet. Do not induce vomiting. Rinse mouth. Never give anything by mouth to an unconscius person.Most important symptoms and effects, both acute and delayedNo additional information available.Indication of any immediate medical attention and special treatment neededNo additional information available.

Fire-fighting measures

Extinguishing mediaCarbon dioxide, dry chemicals, foam, water spray (fog).Special hazards arising from the substance or mixtureIn case of fire, oxides of carbon and nitrogen may be liberated.Advice for fire-fightersWear self-contained breathing apparatus due to dangerous fumes and gases.

Accidental release measures

Personal precautions, protective equipment and emergency proceduresPersonal precautions: Mask with integral filter cartridge type ABEK. Gloves, protective wearEnvironmental precautionsPrevent from entering sewers or the immediate environment.Methods and material for containment and cleaning upRecovery: On soil: Contain spillages and cover with sand or other inert absorbant material. Contain and recover by physical means. Then place them in a container for disposal in accordance with local regulationsReference to other sectionsNo additional information available.

Handling and storage

Precautions for safe handlingPrevention of worker exposure: Arrange for eye wash possibility. Ensure good ventilation.Prevention of fire and explosion: No known hazards.Precautions: No eating, drinking or smoking during handling.Conditions for safe storage, including any incompatibilitiesTechnical measures: Electrical equipment, including lighting, must conform to current legislation.Storage conditions: Recommendations: Keep away from heat. Avoid: Storage exposed to bad weather.Incompatible materials: strong oxidants.Packaging materials: Recommendations: Aluminium internally lacquered, glass.Specific end use(s)Oxidative hair colorant

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

2810

Shipping

Labels:

6.1 - Toxic substances, N - Dangerous for the environment

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

2810

Shipping

Labels:

6.1 - Toxic substances, N - Dangerous for the environment

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

2810

Shipping information

Proper shipping name and description:

TOXIC LIQUID, ORGANIC, N.O.S. ; (2,5 TOLUYLENE DIAMINE, AQUEOUS SOLUTION)

Chemical name:

2-methyl-p-phenylenediamine

Labels:

6.1 - Toxic substances, N - Dangerous for the environment

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

2810

Shipping information

Proper shipping name and description:

Dye intermediate, solid, toxic, n.o.s.

Chemical name:

2-methyl-p-phenylenediamine

Labels:

6.1 - Toxic substances, N - Dangerous for the environment

Remarks

Additional transport information

Additional information

Special provisions / remarks / other:

Internal transport only in original containers or other unbreakable and adequately labelled containers. Keep containers tightly closed and secure by suitable measures against falling down.

Exposure controls / personal protection

Technical measures: Ensure good ventilation. Arrange for eye wash possibility.Respiratory protection: In case of insufficient ventilation, use face mask with breathing filter, type: ABEKHand protection: Protective gloves (Plastic, impervious).Please follow the instructions related to the permeability and the penetration time provided by the manufacturer. The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant standard EN 374Eye protection: Safety goggles/visor (DIN EN 166)Skin protection: Appropriate protective clothing.Hygiene measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands after use. Change contaminated clothing and in any case at the end of work. It is recommended to take a shower at the end of work.

Stability and reactivity

Reactivity:    No additional information available.Chemical stability:    The product is stable under normal storage, handling and usage conditions.Possibility of hazardous reactions:          No additional information available.Conditions to avoid   No known hazard.Incompatible materials   Avoid contact with oxidizers. Avoid contact with metals.Hazardous decomposition products   No additional information available.

Disposal considerations

Disposal of product: Authorized disposal. Dispose of in a safe manner, in accordance with local regulations. Avoid dispersal of spilled material, and runoff and contact with soil, waterways, drains and sewers.Disposal of packaging: Authorized disposal. Recover or destroy according to current local regulations.This material and its container must be disposed of in a safe way. Handle uncleaned and non-rinsed empty containers with care.Empty containers or liners may retain some product residuesAvoid dispersal of spilled material, and runoff and contact with soil, waterways, drains and sewers.