Registration Dossier
Registration Dossier
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EC number: 202-112-7 | CAS number: 91-97-4
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation : Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. If experiencing respiratory symptoms, call a POISON CENTER/doctor.
Skin Contact : Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Eye Contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention.
Ingestion : Wash out mouth with water. Call a POISON CENTER/doctor. Do not give unconscious victim anything to drink.
Fire-fighting measures
Extinguishing media:
Suitable extinguishing media: Carbon dioxide, dry chemical, form or water
Unsuitable extinguishing media : Not known
Special hazards arising from the substance or mixture:
Unusual Fire and Explosion Hazards : Thermal decomposition or combustion may produce carbon monoxide, carbon dioxide and nitrogen oxides.
Advice for firefighters:
Protective equipment : Wear self-contained breathing apparatus and complete personal protective equipment.
Other information : Move containers away from fire areas if it can be done without risk.
If impossible to remove containers from fire zone, cool them with water spray
Accidental release measures
Personal precaution, protective equipment and emergency procedures:
Wear personal protective equipment. Refer to Section 8 for personal protective equipment. Avoid raising dust. Avoid contact with skin, eyes and clothing. Evacuate area. Ventilate area.
Environmental precautions:
Prevent this product from entering into drains, ditches or rivers because it is very toxic to aquatic life. Obey Federal, State or local regulations for health and environment protection to discharge treated water to sea, river or lake etc.
Methods and material for containment and cleaning up:
Sweep or shovel up spill material in dry containers. Wash spill site after material pickup is complete. Obey Federal, State or local regulations for health and environmental protection when discharging treated water to sea, river or lake etc.
Handling and storage
Precautions for safe handling:
Wear personal protective equipment. Refer to Section 8 for personal protective equipment.
Avoid contact with skin, eyes and clothing.
Avoid breathing dust.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Avoid release to the environment.
Conditions for safe storage, including any incompatibilities:
Store in a cool dry place without direct sunshine.
Keep container tightly.
Avoid contact of this product with moisture, water. Moisture or water contamination may result in dangerous.
Specific end use :
The material for urethane resin. Used as intermediate under strictly controlled conditions.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(4,4’- Diisocyanato-3,3’- dimethyl-1, 1’-bipheny1)
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- Environmentally Hazardous Substance, Solid, n.o.s (4,4’- Diisocyanato-3,3’- dimethyl-1, 1’-biphenyl)
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- Not applicable
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- TODI is not transported on inland waterways
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(4,4’- Diisocyanato-3,3’- dimethyl-1, 1’-bipheny1)
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- Environmentally hazardous substance, n.o.s. (4,4’- Diisocyanato-3,3’- dimethyl-1, 1’-biphenyl)
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, solid, n.o.s.
(4,4’- Diisocyanato-3,3’- dimethyl-1, 1’-bipheny1)
- Packing group:
- Packing group III: Substances presenting low danger
- Labels:
- Environmentally hazardous substance, n.o.s. (4,4’- Diisocyanato-3,3’- dimethyl-1, 1’-biphenyl)
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters : TLV/ACGIH (2021) Not listed
Derived no effects levels: No DNELs derived (qualitative risk assessment)
Predicted no effect concentrations: No PNECs derived (no hazard identified)
German occupational exposure limit values: TRGS 900: 0.003 mg PCB/m3 with reference to the inhalable fraction
Peak limitation: Excursion factor 8
Duration 15 min, mean; 4 times per shift; interval 1 hour
Category II - Substances with systemic effects
Exposure controls:
Occupational exposure controls: Use general and/or local exhaust ventilation to control dusts.
Provide safety showers and eyewashes
Individual protection measures, such as personal protective equipment
(a) Eye/face protection : Use safety goggles.
(b) Skin protection : Wear suitable working clothes, hand protection and boots.
Hand protection : Protective Gloves (according to Standard EN 374 with a breakthrough time > 480 min and with basic employee training)
Glove material: e.g. Outside vinyl chloride resin Inside Cotton, rayon
(c) Respiratory protection : Suitable respirator masks (conforming to EN140:2001 with Type A filter or better).
(d) Thermal hazards : None
Environmental exposure controls : Use general and/or local exhaust ventilation .
Provide safety showers and eyewashes
Stability and reactivity
Reactivity:
The specific test data of the reactivity hazards is not available.
Chemical stability:
Stable under normal storage and handling conditions.
Possibility of hazardous reactions:
Hazardous Polymerization does not occur.
Conditions to avoid: In combustion or heating.
Incompatible materials: Water, alcohol and strong bases.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, benzene, hydrogen cyanide, acetaldehyde and acetone.
Disposal considerations
Waste treatment methods
1) Dispose of contents/container as chemical waste according to Federal, State and local laws concerning health and pollution.
2) Do not discharge into waterway or sewer systems unless permission has been obtained by the local authority and suitable dilution has been established.
3) Empty the packaging completely prior to disposal.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
