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EC number: 256-170-3 | CAS number: 44914-03-6
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
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Hydrolysis
Administrative data
Link to relevant study record(s)
Description of key information
Hydrolysis is not expected to contribute significantly to the fate of 2-MBA.
Key value for chemical safety assessment
Additional information
Experimental data for 2-MBA hydrolysis were not available. The related compound n-butyl acrylate (n-BA) was studied using USEPA method 40 CFR Part 796.3500 under GLP criteria. n-BA has an abiotic hydrolytic half-life of 1100 days at pH 7, 25 °C. This study was considered reliable without restrictions for n-BA and is reliable with restrictions as read-across data for 2-MBA. n-BA and 2-MBA are structurally and chemically very similar, differing only in presence or absence of a methyl branch at the 2-carbon of the alcohol group, which is adjacent to the ester bond. 2-MBA is expected to be somewhat less hydrolytically active than n-BA due to steric factors resulting from its methyl branch. In addition, 2-MBA and n-BA (as well as another analog, isooctyl acrylate) are readily biodegradable. We have proposed adaptation (omission) of the data requirement for hydrolysis for 2-MBA, owing to ready biodegradability. 2-MBA would be biodegraded in non-sterile aquatic and terrestrial systems well before abiotic hydrolysis would occur.
Data matrix – Analog approach |
||
Target substance |
Source substance |
|
CHEMICALNAME |
2-methylbutyl acrylate |
n-butyl acrylate |
CAS# |
44914-03-6 |
141-32-2 |
Molecular formula |
C8H14O2 |
C7H12O2 |
Molecular Weight |
142.2 |
128.2 |
PHYSICO-CHEMICAL DATA |
||
Melting Point |
≤ -75 °C |
Not available |
Boiling Point |
161.7 °C at 1013hPa |
147 °C at 1013hPa |
Density |
0.8886 g/cm3 at 25 °C |
0.9 g/cm3 at 20.0 °C |
Vapour Pressure |
1.7 hPa at 20°C |
5 hPa at 22.2°C |
Partition Coefficient (log Kow) |
2.9 |
2.38 (at 25°C) |
Water Solubility |
316 mg/L at 23 °C |
Not available |
ENVIRONMENTAL FATE and PATHWAYS |
||
Photodegradation |
DT50 1.04 d (AOPWIN v1.92) |
Not determined |
Stability in Water |
Adaptation, readily biodegradable |
DT50, 1100 day at pH 7, 25 °C (40CFR796.3500) |
Aerobic Biodegradation |
60% after 11 days (OECD 301D) |
80 - 90% after 28 days (OECD 310) |
Bioconcentration |
Not bioaccumulative |
Not bioaccumulative |
Transport and Distribution |
Koc 263 – 302 (Calculated by TGD method) |
Koc 40-148 (EPA OTS 796.2750) |
Henry's Law constant |
96 Pa*m3/mol at 23.1 °C |
Not determined |
ENVIRONMENTAL TOXICITY |
||
Toxicity to Microorganisms (activated sludge respiration) |
3-hour EC50 >1000 mg/L (OECD 209) |
3d EC50 >150 mg/L (ASTM STP 528) |
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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