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Physical & Chemical properties

Auto flammability

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Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2017-01-18 to 2017-01-20
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Version / remarks:
2008
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Version / remarks:
2003
Qualifier:
according to guideline
Guideline:
DIN EN 14522, Method P (Determination of the auto ignition temperature of gases and vapours)
Version / remarks:
2005
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
- Name of test material (as cited in study report): n-Butyl Glycidyl Ether
- Appearance: clear, colourless liquid
- Batch No.: 16081440
- Purity: 99.2%
- Storage conditions: ambient temperature
- Expiry date: 2019-10-12
Key result
Auto-ignition temperature:
255 °C
Atm. press.:
1 022 hPa

Based on results of the main test series, the auto-ignition temperature rounded down to the nearest multiple of 5 °C was determined as 255 °C.

- EC No. 440/2008 and DIN 51794: the auto-ignition temperature rounded down to the nearest multiple of 5 °C was determined as 255 °C.

- DIN EN 14522: the auto-ignition temperature reduced by 1.5% and rounded to the nearest integer temperature was determined as 256 °C.

Table: main test, lowest temperature at which an ignition occurred.

Main test series

Lowest temperatures of an ignition

Highest temperatures without an ignition

Atmospheric Pressure

1

260 °C

257 °C

1022.5 – 1025.4 hPa

2

261 °C

257 °C

1022.0 hPa

3

261 °C

257 °C

1021.5 hPa

Table: results of the preliminary test

 

Preliminary test

Temperature (°C)

201

251

302

292

282

271

Ignition (+/-)

-

-

+

+

+

-

 

Atmospheric pressure: 1025.6 hPa

Description of key information

The auto-ignition temperature (liquids) was determined to be 255 °C.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
255 °C

Additional information

The auto-ignition temperature was determined in a study according to EC No. 440/2008 Method A.15 and in compliance with GLP criteria. In this study the lowest temperature at which a gas/air- or vapour/air-mixture of the flammable test item ignites in contact with a hot surface was determined. This is assessed by varying the amount of test item and the test temperature. The lowest temperature is rounded down to the nearest multiple of 5 °C. The auto-ignition temperature was determined to be 255 °C.